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首页> 外文期刊>Catalysis for Sustainable Energy >Production of bio-aromatics from ethanol-waste cooking oil mixtures over ZSM-5 catalyst material
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Production of bio-aromatics from ethanol-waste cooking oil mixtures over ZSM-5 catalyst material

机译:在ZSM-5催化剂材料上由乙醇-废烹饪油混合物生产生物芳烃

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摘要

The utilisation of ethanol-waste cooking oil (Eth- WCO) mixtures for the production of valuable chemicals has been considered. The study investigated the potential of synthesised HZSM-5 in the conversion of ethanol-oil mixtures to fuel-range hydrocarbons. HZSM-5 catalyst material was successfully synthesised and characterised and activities were tested in a fixed-bed reactor unit at temperatures of 400°C and 450 °C with a fixed weight hourly space velocity of 2.5 h-1 at atmospheric pressure. The synthesised catalyst had total surface area greater than 250 m2/g. From the catalyst activity test, it was observed that up to 93% conversion was achieved on the synthesised catalysts. The conversion product was rich in aromatic compounds such as p-xylene, toluene and naphthalene that have potential as feedstock in the chemical and petrochemical industries. The FeZSM-5 catalyst material had a generally higher percentage composition of p-xylene content, peaking at 30% at 400°C for pure waste cooking oil feedstock. Potential catalysts for bio-aromatics production from ethanol-waste cooking oil mixtures have been successfully synthesised and evaluated.
机译:已经考虑将乙醇-废烹饪油(Eth-WCO)混合物用于生产有价值的化学品。该研究调查了合成的HZSM-5在将乙醇-油混合物转化为可燃范围的烃方面的潜力。 HZSM-5催化剂材料已成功合成和表征,并在固定床反应器单元中于400°C和450°C的温度下在大气压力下以2.5 h-1的固定重小时空速测试了活性。合成的催化剂的总表面积大于250平方米/克。从催化剂活性测试,观察到在合成的催化剂上达到了高达93%的转化率。该转化产物富含芳族化合物,例如对二甲苯,甲苯和萘,在化工和石化工业中有作为原料的潜力。 FeZSM-5催化剂材料通常具有较高的对二甲苯成分百分比,对于纯废食用油原料,其在400°C时达到30%的峰值。已经成功地合成和评估了从乙醇-废食用油混合物中生产生物芳烃的潜在催化剂。

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