Design and synthesis of chalcone-based macrocyclic polyethers

Subrata Jana

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Design and synthesis of chalcone-based macrocyclic polyethers

机译：查尔酮基大环聚醚的设计与合成

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A series of chalcone-based macrocyclic ethers have been synthesized. These macrocyclic ethers contain polyether as well as extended conjugation to the benzene ring to function as fluorescent sensor for cations. The modeling studies show that the chalcone part of the receptors remains partially out of plane from the polyether part and the keto moiety of the receptors always directed outwardly in the receptor itself. This may be changed during the recognition of metal ions. The tendency of the fluorophore, to be out of plane, increases with increasing the ring size.

机译：已经合成了一系列基于查尔酮的大环醚。这些大环醚含有聚醚以及与苯环的扩展共轭，可充当阳离子的荧光传感器。模拟研究表明，受体的查耳酮部分与聚醚部分保持部分不在平面内，并且受体的酮基始终朝着受体本身向外。在识别金属离子的过程中可能会改变。荧光团在平面外的趋势随着环尺寸的增加而增加。

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《Cogent Chemistry》 |2015年第1期|共8页
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3. Synthesis and Characterization of Macrocyclic Polyether N,N'-Dially1-7,16-diaza-1,4,10,13-tetraoxadibenzo-18-crown-6 [J] . Toeri Julius, Laborie Marie-Pierre Molecules . 2016,第2期

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4. Chemoselective Synthesis of Novel Macrocyclic Polyether 60 Fullerene bis- and tris-Adducts by Tether-Directed Chemistry and Study of their Complexation Behavior with Alkali Metal Cations [C] . Zhiguo Zhou, David I. Schuster, Stephen R. Wilson International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters, May 12-17, 2002, Philadelphia . 2002

机译：系链导向化学化学选择性合成新型大环聚醚60富勒烯双-和三-加合物及其与碱金属阳离子的络合行为研究
5. Macrocyclic chemistry: Part I - Characterization of a mixed-valence di-iron complex and synthesis of a new poly-iron complex. Part II - Synthesis, characterization of new diphosphoester macrocyclic polyethers. [D] . Hoang, Son Xuan. 2011

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7. Design and synthesis of chalcone-based macrocyclic polyethers [O] . Subrata Jana 2015

机译：基于查尔酮的大环聚醚的设计与合成
8. Chemistry of Optically Active Macrocyclic Polyethers [R] . Ghirardelli, R. G., Palmer, R. A. 1985

机译：光学活性大环聚醚的化学

Design and synthesis of chalcone-based macrocyclic polyethers

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