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Novel Electronic State and Superconductivity in the Electron-Doped High-Tc Ta??-Superconductors

机译:电子掺杂的高Ta-Ta超导体中的新型电子态和超导性

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In this review article, we show our recent results relating to the undoped (Ce-free) superconductivity in the electron-doped high- T c cuprates with the so-called Ta?? structure. For an introduction, we briefly mention the characteristics of the electron-doped Ta??-cuprates, including the reduction annealing, conventional phase diagram and undoped superconductivity. Then, our transport and magnetic results and results relating to the superconducting pairing symmetry of the undoped and underdoped Ta??-cuprates are shown. Collaborating spectroscopic and nuclear magnetic resonance results are also shown briefly. It has been found that, through the reduction annealing, a strongly localized state of carriers accompanied by an antiferromagnetic pseudogap in the as-grown samples changes to a metallic and superconducting state with a short-range magnetic order in the reduced superconducting samples. The formation of the short-range magnetic order due to a very small amount of excess oxygen in the reduced superconducting samples suggests that the Ta??-cuprates exhibiting the undoped superconductivity in the parent compounds are regarded as strongly correlated electron systems, as well as the hole-doped high- T c cuprates. We show our proposed electronic structure model to understand the undoped superconductivity. Finally, unsolved future issues of the Ta??-cuprates are discussed.
机译:在这篇评论文章中,我们显示了我们最近的结果,这些结果与电子掺杂的高T c铜酸盐中的未掺杂(不含Ce的)超导有关,即所谓的Ta?结构体。作为介绍,我们简要地提到掺杂电子的Ta +-铜酸盐的特性,包括还原退火,常规相图和未掺杂的超导性。然后,显示了我们的输运和磁学结果,以及与未掺杂和未掺杂的Ta +-铜酸盐的超导配对对称有关的结果。还简要显示了协作光谱和核磁共振结果。已经发现,通过还原退火,在所生长的样品中伴随反铁磁伪间隙的载流子的强定位状态在还原的超导样品中变为具有短距离磁序的金属和超导状态。在还原的超导样品中由于极少量的过量氧气而形成的短程磁阶表明,在母体化合物中表现出未掺杂超导性的Ta +-铜酸盐被认为是强相关的电子系统,以及空穴掺杂的高T c铜酸盐。我们展示了我们提出的电子结构模型,以了解未掺杂的超导性。最后,讨论了未解决的Ta + -cuprates的未来问题。

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