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Sonocatalysis degradation of methyl orange using zinc sulfide carbon nanotubes nanocatalyst

机译:硫化锌碳纳米管纳米催化剂声催化降解甲基橙

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Dye sewage is dangerous problem in our environmental aquatics that cause generation of harmful effects for living organism. In this work, because of simplicity, easy operation, high efficiency and no creating secondary pollutants, ultra sound radiation applied for degradation of a synthetic dye, methyl orange using zinc sulfide nano particles decorated on carbon nanotubes as nanocatalyst. ZnS/CNTs prepared by co-precipitation of carbon nanotubes and zinc aceate. Methyl orange (MO) is a cationic dye that used widely in some medical uses, coloring paper, dyeing cottons, wools, coating for paper stocks and etc. For achieving highest degradation efficiency several parameters such as pH, amount of nanocatalyst, initial dye concentration and time were evaluated and optimized. Results showed that highest degradation efficiency (100%) obtained at 0.3 gr of nanocatalyst while initial dye concentration is 30 mg/L at pH, 2. Comparison of several methods for degradation of methyl orange showed feasibility of applied method. In addition, reusability of nanocatalyst was suitable for degradation of MO in real wastewater samples.
机译:染料废水是我们环境水生生物中有害影响的危险问题。在这项工作中,由于简单,易于操作,效率高且不产生二次污染物,因此将超声波辐射应用于降解合成染料,使用装饰在碳纳米管上的硫化锌纳米颗粒作为甲基催化剂的甲基橙。通过碳纳米管和乙酰乙酸锌的共沉淀制备的ZnS / CNT。甲基橙(MO)是一种阳离子染料,广泛用于某些医疗用途,着色纸,染色棉,羊毛,纸料涂料等。为了获得最高的降解效率,几个参数(例如pH值,纳米催化剂的量,初始染料浓度)和时间进行了评估和优化。结果表明,当pH值为2时,初始染料浓度为30 mg / L时,在0.3 gr纳米催化剂上可获得最高的降解效率(100%)。比较几种降解甲基橙的方法表明了该方法的可行性。此外,纳米催化剂的可重复使用性适合降解实际废水样品中的MO。

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