Substrate-Selective C–H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components

Konstantin V. Luzyanin; Aleksei N. Marianov; Pavel G. Kislitsyn; Valentine P. Ananikov

首页> 外文期刊>ACS Omega >Substrate-Selective C–H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components

【24h】

Substrate-Selective C–H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components

机译：从原油衍生成分制备有机硫化合物的底物选择性C–H功能化

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The direct utilization of a natural feedstock in organic synthesis is an utmost challenge because the selective production of one product from a mixture of starting materials requires unprecedented substrate selectivity. In the present study, a simple and convenient procedure is evaluated for the substrate-selective alkenylation of a single component in a mixture of organosulfur compounds. Pd-catalyzed alkenylation of two-, three-, four-, and five-component mixtures of crude oil-derived sulfur species led to the exclusive C–H functionalization of only one compound. The observed remarkable substrate selectivity opens new opportunities for sustainable organic synthesis.

机译：在有机合成中直接利用天然原料是最大的挑战，因为从起始原料的混合物中选择性生产一种产品需要前所未有的底物选择性。在本研究中，评估了一种简单方便的程序，用于有机硫化合物混合物中单个组分的底物选择性烯基化。钯衍生的原油衍生的硫组分的二，三，四和五组分混合物的烯基化导致仅一种化合物的独家CH功能化。观察到的出色的底物选择性为可持续的有机合成开辟了新的机会。

著录项

来源
《ACS Omega》 |2017年第4期|共5页
作者
Konstantin V. Luzyanin; Aleksei N. Marianov; Pavel G. Kislitsyn; Valentine P. Ananikov;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Organosulfur-functionalized Au, Pd, and Au-Pd nanoparticles on 1D silicon nanowire substrates: Preparation and XAFS studies [J] . Zhang P, Zhou XT, Tang YH, Langmuir: The ACS Journal of Surfaces and Colloids . 2005,第18期

机译：一维硅纳米线基板上有机硫官能化的Au，Pd和Au-Pd纳米颗粒：制备和XAFS研究
2. Organosulfur-functionalized Au, Pd, and Au-Pd nanoparticles on 1D silicon nanowire substrates: Preparation and XAFS studies [J] . Zhang P, Zhou XT, Tang YH, Langmuir: The ACS Journal of Surfaces and Colloids . 2005,第18期

机译：一维硅纳米线基板上有机硫官能化的Au，Pd和Au-Pd纳米颗粒：制备和XAFS研究
3. Improved method for simultaneous determination of saturated and aromatic biomarkers, organosulfur compounds and diamondoids in crude oils by GC–MS/MS [J] . Mei Mei, K.K. (Adry) Bissada, Thomas B. Malloy, Organic Geochemistry: A Publication of the International Association of Geochemistry and Cosmochemistry . 2018,第期

机译：通过GC-MS / MS同时测定原油中饱和和芳族生物标志物，有机硫磺化合物和表情的方法
4. Electrochemical Behavior of Organosulfur Compound having various functional groups in an Organic Electrolyte Solution [C] . Seok Kim, Yongju Jung, Yunsuk Choi The Meeting of the Electrochemical Society . 2001

机译：有机硫磺化合物在有机电解质溶液中具有各种官能团的电化学行为
5. Mass spectrometric studies on petroleum asphaltenes and organosulfur compounds, on functional-group selective ion-molecule reactions and on gas-phase reactivity of meta-benzynes toward amino acids [D] . Tang, Weijuan 2015

机译：石油沥青质和有机硫化合物，官能团选择性离子分子反应以及间苯甲酸酯对氨基酸的气相反应性的质谱研究
6. Substrate-Selective C–H Functionalization forthe Preparation of Organosulfur Compounds from Crude Oil-Derived Components [O] . KonstantinV. Luzyanin, Aleksei N. Marianov, Pavel G. Kislitsyn, 2017

机译：底物选择性C–H功能化原油衍生成分制备有机硫化合物
7. Substrate-Selective C–H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components [O] . Luzyanin KV, Marianov AN, Kislitsyn PG, 2017

机译：从原油衍生成分制备有机硫化合物的底物选择性C–H功能化
8. Heats of Formation of Gas Phase Organosulfur Molecules, Radicals and Ions Measured by PEPICO, and Application of exp 17 O and exp 33 S NMR Spectroscopy to Structure Determinations of Organosulfur Compounds. Progress Report, June 1984-March 1985. [R] . Baer, T., Evans, S. A. 1985

机译：用pEpICO测定气相有机硫分子，自由基和离子的生成热，以及exp 17 O和exp 33 s NmR光谱法在有机硫化合物结构测定中的应用。进展报告，1984年6月至1985年3月。

Substrate-Selective C–H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components

摘要

著录项

相似文献

相关主题

期刊订阅