...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>ACS Omega >Macromolecular Probe Based on a NiII/TbIII Coordination Polymer for Sensitive Recognition of Human Serum Albumin (HSA) and MnO4–
【24h】

Macromolecular Probe Based on a NiII/TbIII Coordination Polymer for Sensitive Recognition of Human Serum Albumin (HSA) and MnO4–

机译：基于NiII / TbIII配位聚合物的大分子探针，用于敏感识别人血清白蛋白（HSA）和MnO4–

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Reported here are the design and fluorescence characters of a NiII/TbIII polymer, [Tb2Ni3(HCAM)6(H2O)12]n (1) (H3CAM = chelidamic acid). Under physiological conditions, the binding of biocompatible water soluble 1 to human serum albumin (HSA) was studied by spectroscopy techniques, which revealed that 1 could inherent the fluorescent light of HSA in a static quencher course and change the HSA second-level structure. The marked enhancement in 1 and its fluorescence intensity provide conclusive evidence that 1 can play the role of a “turn-on” sensor for recognition and detection of HSA in other biological interferents with a Ksv value of 7.68 × 104 M–1 and a detection limit of 0.14 μM. Luminescence experiments show that 1 has high selectivity and sensitivity to MnO4– in other anions. Its quenching efficiency (Ksv) is 5.54 × 103 M–1, and the detection limit is 0.29 μM.
机译：此处报道的是NiII / TbIII聚合物[Tb2Ni3（HCAM）6（H2O）12] n（1）（H3CAM =氯胺酸）的设计和荧光特性。在生理条件下，通过光谱技术研究了生物相容性水溶性1与人血清白蛋白（HSA）的结合，结果表明1可以在静态淬灭过程中固有地存在HSA的荧光并改变HSA二级结构。 1的显着增强及其荧光强度提供了确凿的证据，表明1可以起到“开启”传感器的作用，以识别和检测其他生物干扰物中的HSA，其Ksv值为7.68×104 M-1，并进行检测极限为0.14μM。发光实验表明1在其他阴离子中对MnO4-具有很高的选择性和敏感性。其淬灭效率（Ksv）为5.54×103 M–1，检出限为0.29μM。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号