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首页> 外文期刊>American journal of applied sciences >DYEABILITY AND MECHANICAL PROPERTIES OF ACRYLONITRILE-DIALLYLAMINE SALTS COPOLYMERS | Science Publications
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DYEABILITY AND MECHANICAL PROPERTIES OF ACRYLONITRILE-DIALLYLAMINE SALTS COPOLYMERS | Science Publications

机译:丙烯腈-二烯丙胺盐类共聚物的可塑性和力学性能科学出版物

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> The dyeability of Acrylonitrile-Diallylamine Acetate (AN-DAA acetate) and Acrylonitrile-Diallylguanidine Acetate (AN-DAGA) copolymers have been studied with both conventional and ultrasonic methods. The results obtained were compared to the parent polyacrylonitrile. The effect of dye concentration, dye bath pH, dyeing time and temperature were studied and the results obtained by dyeing with both techniques were compared. Color strength values were found to be higher with ultrasonic than with conventional method. To identify the structural changes in the dyed copolymers as compared to dyed PAN, during thermal treatment at high temperature, XRD analysis were performed. The XRD patterns of all heated dyed copolymers are similar to the corresponding unheated samples while that of the heated dyed PAN changed dramatically. The mechanical properties of the dyed copolymers had been also studied and compared to those of the dyed PAN.
机译: >用常规方法和超声方法都研究了丙烯腈-二烯丙胺乙酸酯(AN-DAA乙酸酯)和丙烯腈-二烯丙胍乙酸酯(AN-DAGA)共聚物的可染性。将获得的结果与母体聚丙烯腈进行比较。研究了染料浓度,染浴pH,染色时间和温度的影响,并比较了两种技术染色的结果。发现超声强度显着高于常规方法。为了确定染色的共聚物与染色的PAN相比的结构变化,在高温热处理期间,进行了XRD分析。所有加热的染色共聚物的XRD图谱与相应的未加热样品相似,而加热的染色PAN的XRD图谱则发生了巨大变化。还研究了染色共聚物的机械性能,并将其与染色PAN的机械性能进行了比较。

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