...
首页> 外文期刊>American Journal of Analytical Chemistry >Adsorption and Leaching Potential of Imidacloprid Pesticide through Alluvial Soil
【24h】

Adsorption and Leaching Potential of Imidacloprid Pesticide through Alluvial Soil

机译:吡虫啉农药在冲积土中的吸附和淋溶潜能

获取原文
           

摘要

This study was aimed to assess the adsorption and leaching potential of imidacloprid pesticide in column and field soil. To visibly understand these actions and factors affecting them, the experiments were carried out under laboratory and field conditions. Adsorption study was divided into kinetic and equilibrium sections. The evaluation of kinetic data was done through pseudo first and second order models. It was found that kinetic adsorption of imidacloprid on soil followed pseudo second order with rate constant value of 4.333 mg/g/h. Langmuir and Freundlich isotherms were used to explain equilibrium adsorption, from these isotherms it was evaluated that Freundlich isotherm was obeyed well with adsorption capacity of 2.190 - 4.573 mol/g. Leaching study was performed in laboratory using column made of poly-vinyl chloride having 30 cm length. Known amount of imidacloprid pesticide was applied to column left for adsorption and then eluted with 500 mL water in five equal portions. These water portions and soil of column which was divided into three sections were analyzed by HPLC. The result revealed that the concentration of imidacloprid was decreased from 0.481 ppm in first portion of water to 0.327 ppm in last portion of water while 0.783 ppm in first section of column soil to 0.038 ppm in last section of column soil. In field the leaching power of imidacloprid was observed up to 60 cm depth, its concentration decreased with soil depth. It was 3.311 ppm in first portion of soil and 0.357 ppm in last portion of soil. The leaching potential of imidacloprid pesticide up to 60 cm soil depth was due to less organic matter, sandy texture, alkaline pH, and low cation exchange capacity.
机译:这项研究旨在评估吡虫啉农药在田间和田间土壤中的吸附和浸出潜力。为了清楚地了解这些动作和影响它们的因素,在实验室和野外条件下进行了实验。吸附研究分为动力学部分和平衡部分。通过伪一级和二级模型对动力学数据进行评估。发现吡虫啉在土壤上的动力学吸附遵循假二级,速率常数值为4.333 mg / g / h。用Langmuir和Freundlich等温线解释了平衡吸附,从这些等温线中可以很好地遵守Freundlich等温线,吸附容量为2.190-4.573 mol / g。在实验室使用长度为30 cm的聚氯乙烯制成的色谱柱进行浸出研究。将已知量的吡虫啉农药加到残留的色谱柱上进行吸附,然后用500 mL水等分成五个部分洗脱。通过HPLC分析分成三部分的这些水部分和柱土。结果表明,吡虫啉的浓度从水的第一部分中的0.481ppm降低到水的最后部分中的0.327ppm,而柱土的第一部分中的0.783ppm降低至柱土的最后部分中的0.038ppm。在田间,观察到吡虫啉的浸出力高达60 cm深度,其浓度随土壤深度而降低。在土壤的第一部分中为3.311 ppm,在土壤的最后部分中为0.357 ppm。吡虫啉农药在土壤深达60 cm时的浸出潜力是由于有机物较少,沙质质地,碱性pH值和低阳离子交换能力所致。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号