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首页> 外文期刊>American Journal of Analytical Chemistry >Determination of Apparent Formation Constants of Eu(III) with Humic Substances by Ion Selective Liquid Membrane Electrode
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Determination of Apparent Formation Constants of Eu(III) with Humic Substances by Ion Selective Liquid Membrane Electrode

机译:离子选择性液膜电极测定腐殖质中Eu(III)的表观形成常数

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This is the novel measurement of the apparent formation constants of trivalent lanthanide with humic substances by potentiometric titration using an ion selective electrode (ISE) consisting of bis(diphenylphosphoryl)methane as an ionophore. The ISE prepared exhibited a Nernstian response to the Eu3+ concentration in the test solutions in the presence of humic acid and fulvic acid. The effect of the solution conditions, including the pH, initial metal and humic substance concentrations, and ionic strength, on the formation constants was examined. The present formation constants were compared with the reported data using solvent extraction method.
机译:这是通过使用由双(二苯基磷酰基)甲烷组成的离子选择电极(ISE)作为电位计,通过电位滴定法对腐殖质中三价镧系元素的表观形成常数的新颖测量。所制备的ISE在腐殖酸和富里酸存在下,对测试溶液中Eu3 +的浓度表现出能斯特响应。研究了溶液条件(包括pH,初始金属和腐殖质浓度以及离子强度)对形成常数的影响。使用溶剂萃取法将当前的形成常数与报道的数据进行比较。

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