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Analysis of atmospheric neutral and charged molecular clusters in boreal forest using pulse-height CPC

机译:脉冲高度CPC分析北方森林大气中性和带电分子团簇

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We measured the size distribution of atmospheric neutral and chargedclusters and particles down to mobility diameter around 1.5 nm by applyingpulse-height CPC technique at SMEAR II station in Hyyti?l?, southernFinland during spring 2007 and May 2008. The concentration of molecularclusters smaller than 3 nm seems to be highly variable in boreal forestenvironment, the concentration varied typically between 500–50 000 cm−3.By comparing to concentrations measured with ion spectrometers,we conclude that ion clusters and neutral clusters produced by ion-ionrecombination are usually not sufficient to explain all of the observedclusters; the median fraction of recombination products from all neutralclusters was 4.9%. Before and during most new particle formation eventsthe cluster formation rate rose only slightly, or remained close to stable.Nocturnal formation of clusters was also frequently observed.
机译:我们在2007年春季和2008年5月期间,通过在南部芬兰Hyyti?l?的SMEAR II站采用脉冲高度CPC技术,测量了大气中性和带电团簇以及粒径小于1.5 nm的粒子的尺寸分布。分子团簇的浓度小于3在北方森林环境中,nm似乎变化很大,浓度通常在500-50000 cm −3 之间变化。与离子光谱仪测得的浓度相比,我们得出结论:离子产生的离子簇和中性簇-离子重组通常不足以解释所有观察到的簇;来自所有中性簇的重组产物的中位数分数为4.9%。在大多数新的颗粒形成事件之前和期间,团簇形成速率仅略有上升,或保持接近稳定。还经常观察到团簇的夜间形成。

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