State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310032, P.R. China

Fengming Zhao; Fei Yan; Yang Qian; Youqun Chu; Chun’an Ma

首页> 外文期刊>International Journal of Electrochemical Science >State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310032, P.R. China

【24h】

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310032, P.R. China

机译：浙江工业大学化工与材料学院绿色化学合成技术国家重点实验室培育基地，杭州310032

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

TiO2 film was prepared by in-situ anodic oxidation on a polished titanium sheet in a mixed acidsolution containing 1.0 mol/l sulfuric acid and 1.0 mol/l maleic acid. By means of polar conversiontechnology, succinic acid was synthesized using a TiO2 film as cathode in the original solution. Thereduction yield and current efficiency of succinic acid were 99.36% and 97.52%, respectively. Theelemental composition, valence state analysis and superficial morphology of TiO2 film cathode beforeand after electrolysis were characterized by XPS and SEM. The electrocatalytic properties of TiO2 filmelectrode towards the electrocatalytic reduction of maleic acid to succinic acid were evaluated by CVand galvanostatic electrolysis experiments. Experimental evidence was presented that porous TiO2 filmcathode exhibited powerful electrocatalytic activity for the reduction of maleic acid. Furthermore, asynergistic effect of low valent titanium of Ti(III) and chemisorbed hydrogen (H)Ti was proposed forprobable reductive mechanism of malaeic acid to succinic acid.

机译：通过在含有1.0 mol / l硫酸和1.0 mol / l马来酸的混合酸溶液中在抛光的钛板上进行原位阳极氧化来制备TiO2膜。通过极性转化技术，在原始溶液中以TiO2薄膜为阴极合成琥珀酸。琥珀酸的产率和电流效率分别为99.36％和97.52％。用XPS和SEM表征了TiO2薄膜阴极电解前后的元素组成，价态分析和表面形貌。通过CV和恒电流电解实验评价了TiO2薄膜电极对马来酸还原为琥珀酸的电催化性能。实验证明，多孔TiO2薄膜阴极对马来酸的还原具有强大的电催化活性。此外，提出了低价钛（III）和化学吸附的氢（H）Ti的协同作用，可能是苹果酸还原为琥珀酸的机理。

著录项

来源
《International Journal of Electrochemical Science》 |2012年第12期|共10页
作者
Fengming Zhao; Fei Yan; Yang Qian; Youqun Chu; Chun’an Ma;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类化学;
关键词
入库时间 2022-08-18 08:58:38

相似文献

外文文献
中文文献
专利

1. The College of Energy and Power Engineering, Inner Mongolia University of Technology,010051Hohhot,China 2 Key Laboratory of Wind Energy and Solar Energy Technology (Inner Mongolia University of Technology), Ministry of Education [J] . Ataman Altug Atici, Mahmut Elpz, Fazil Sen Fresenius environmental bulletin . 2018,第10期

机译：内蒙古工业大学能源与动力工程学院，呼和浩特010051 2教育部风能与太阳能技术重点实验室（内蒙古工业大学）
2. Fingerprinting and variety identification of rice (Oryza sativa L.) based on simple sequence repeat markers Yan-fang Zhu, Guo-chen Qin, Jin Hu, Yang Wang, Jian-cheng Wang and Shui-jin Zhu Seed Science Center, College of Agriculture and Biotechnology, Zhejiang University, Hangzhou 310058, China Abstract [J] . Plant Omics . 2012,第1期

机译：基于简单序列重复标记的指纹和各种鉴定闫 - 方朱，郭晨秦，金虎，杨王，王王和水金朱种子科学中心，农业学院和生物技术，浙江大学，杭州310058，中国摘要
3. Hydrocracking of n-decane over non-sulfided Ni-Cs_xH_(3-x)PW_(12)O_(40)/Al2O3 catalysts NHao JinDState Key Laboratory for Physical Chemistry of the Solid Surfaces, Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 3SW05, PR China [J] . Xiaodong Yi, Suhua Sun Fuel Processing Technology . 2012,第Null期

机译：正癸烷在未硫化的Ni-Cs_xH_（3-x）PW_（12）O_（40）/ Al2O3催化剂上的加氢裂化N Hao JinD 固体表面物理化学国家重点实验室，绿色化学生产工程实验室厦门大学化学化工学院，醇，醚，酯研究室，厦门3SW05
4. Influence of Superplasticizer and Shrinkage-reducing Admixtures on Early Age Shrinkage of Concrete N^Xiao-Qian QianCollege of civil engineering architecture, Zhejiang University, HangZhou, 310027, P.R. ChinaMqianxq@civil,zju.edu.cn [C] . Shu-Lin Zhan, Yao-Tai Zhu International Symposium on Ultra-High-Pumpability and High Performance Concrete Technology . 2009

机译：超级塑化机和收缩减少混凝土对混凝土初期收缩的影响N ^晓谦倩浙江大学土木工程与建筑学院，杭州，310027，P.R.Chinam Qianxq @ Civil，Zju.edu.cn
5. Current State of the Assets in the Chemical Engineering Laboratory at Rose-Hulman Institute of Technology and Their Use in the Undergraduate Laboratory Course Sequence [D] . Adams, Matthew Elliott. 2017

机译：Rose-Hulman理工学院化学工程实验室的资产现状及其在本科生实验课程中的使用
6. Green materials science and engineering reduces biofouling: approaches for medical and membrane-based technologies [O] . Kerianne M. Dobosz, Kristopher W. Kolewe, Jessica D. Schiffman 2020

机译：绿色材料科学与工程减少生物污染：医疗和膜技术的方法
7. Doctoral Programs: Chemical Engineering : Physics and Chemical Technologies : Computer Science and Engineering : Information Technologies and CAD systems : Electrical energy and thermal power energy : Machine-Building Technology : Welding Technologies : Lifting Appliance and Robots : Materials Technology : Materials Science [O] . 2015

机译：博士学位：化学工程：物理与化学技术：计算机科学与工程：信息技术和CAD系统：电能和热能：机械制造技术：焊接技术：起重设备和机器人：材料技术：材料科学
8. Laboratory of Engineering Geology and Geophysics, Department of Materials Science211 and Rock Engineering, Helsinki University of Technology Annual Report 1998 [R] . Tammenmaa, J. 1999

机译：工程地质与地球物理实验室，材料科学系211和岩石工程，赫尔辛基理工大学1998年年度报告

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310032, P.R. China

摘要

著录项

相似文献

相关主题

期刊订阅