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Nonenzymatic Electrochemical Sensor Based on PdAu Nanoflowers for the Detection of Hydrogen Peroxide

机译:基于PdAu纳米花的非酶电化学传感器检测过氧化氢

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In this work, PdAu nanoflowers was synthesized and used to fabricate hydrogen peroxide sensor. Thesensor was fabricated by simple dropping of the mixed solution of chitosan and PdAu nanoflowers ona glassy carbon electrode. Using electrochemical impedance spectroscopy and cyclic voltammetry, wecharacterized the modified electrode. The proposed sensor exhibited a good performance due to theexcellent electrocatalytic activity of PdAu nanoflowers toward H 2 O 2 in a wide linear range from 0.05to 12 mM with a low detection limit of 1.5 μM (S/N=3). Moreover, the proposed sensor exhibitedsatisfying reproducibility and stability. The practical application of the nonenzymatic sensor wasinvestigated via determination of H 2 O 2 in real disinfected fetal bovine serum samples.
机译:在这项工作中,PdAu纳米花被合成并用于制造过氧化氢传感器。传感器是通过将壳聚糖和PdAu纳米花的混合溶液简单滴入玻璃碳电极上而制成的。使用电化学阻抗谱和循环伏安法,对改性电极进行了表征。所提出的传感器表现出良好的性能,这是由于PdAu纳米花在0.05至12 mM的宽线性范围内对H 2 O 2具有出色的电催化活性,并且检测限低至1.5μM(S / N = 3)。此外,所提出的传感器表现出令人满意的再现性和稳定性。通过测定实际消毒的胎牛血清样品中的H 2 O 2来研究非酶传感器的实际应用。

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