首页> 外文期刊>International Journal of Electrochemical Science >Corrosion Inhibition of 316L Stainless Steel in LiBr+Etileneglycol+H2O By Using Inorganic Inhibitors
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Corrosion Inhibition of 316L Stainless Steel in LiBr+Etileneglycol+H2O By Using Inorganic Inhibitors

机译:无机缓蚀剂对316L不锈钢在LiBr +乙二醇+ H 2 O中的缓蚀作用

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A study of the corrosion inhibition of 316L type stainless steel in LiBr (614 g/l) + ethylene-glycol+H2O by using inorganic inhibitors has been carried out by using potentiodynamic polarizationcurves, free corrosion measurements and linear polarization resistance measurements. Inhibitors0 include LiNO3, Li2MoO4 and Li2CrO4 at concentrations of 5, 20 and 50 ppm and at 25, 50 and 80 C.Polarization curves showed that the addition of 5 ppm of either inhibitor did not affect the corrosionbehavior of 316L SS. However, with the addition of higher inhibitor concentrations, both the corrosionand passivation current density values increased, reaching the highest values with the addition of 20ppm, but the passive region was widened and the pitting potential value was increased. At 25 and0 0 50 C the passive behavior of the steel was kept but it did not exist at 80 C. For long time testing, linearpolarization resistance measurements showed that the corrosion rate was not increased with theaddition of either 5 or 20 ppm but it decreased with the addition of 50 ppm of inhibitor. The corrosionresistance decreased with increasing the temperature but the inhibitor efficiency increased. Nitrateshad a slightly better performance than nitrates and molybdates.
机译:通过使用电位动力学极化曲线,自由腐蚀测量和线性极化电阻测量,研究了使用无机抑制剂对316L型不锈钢在溴化锂(614 g / l)+乙二醇+水中的腐蚀抑制作用。抑制剂包括浓度为5、20和50 ppm以及在25、50和80 C的LiNO3,Li2MoO4和Li2CrO4。极化曲线表明,添加5 ppm的任何一种抑制剂均不会影响316L SS的腐蚀行为。但是,随着抑制剂浓度的增加,腐蚀和钝化电流密度值均增加,在添加20ppm时达到最高值,但钝化区域变宽,点蚀电位值增加。在25和0 0 50 C时,钢保持了被动性能,但在80 C时不存在。对于长期测试,线性极化电阻测量表明,添加5或20 ppm时,腐蚀速率并未增加,但降低了。加入50 ppm的抑制剂。耐腐蚀性随温度的升高而降低,但阻聚剂的效率提高。硝酸盐的性能比硝酸盐和钼酸盐略好。

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