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Facile two-step Electrodeposition Synthesis of CuO Nanowires for Ultrasensitive Non-Enzymatic Sensing of Glucose

机译:便捷的两步电沉积合成CuO纳米线,用于葡萄糖的超灵敏非酶感测

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In this manuscript, well-defined copper(II) oxide nanowires (CuO NWs) structures were successfullysynthesized by simple, template- and surfactant-free two-step electrodeposition method. The obtainedCuO NWs were investigated using field emission scanning electron microscopy (FESEM) and X-rayphotoelectron spectroscopy (XPS). The electrochemical properties of the CuO NWs modified glassycarbon (CuO NWs/GC) electrode towards nonenzymatic detection of glucose (Glc) under alkalineconditions were studied by cyclic voltammetry (CV) and chronoamperometry. Excellentelectroreduction activity of CuO NWs towards Glc was observed. The CuO NWs/GC sensor wascharacterized by the wide linear range for Glc (0.0125-4.29 mM), high sensitivity (759.86 μA mM ?1cm ?2 ), short response time (4s) and the low limit of detection (LOD = 4.17 μM). Moreover, the sensorshowed good reproducibility, anti-interferant ability and long-term stability. Hence it suggests a potentialapplicability of CuO NWs/GC as a sensor for nonenzymatic detection and quantification of glucose.
机译:在此手稿中,通过简单,无模板和无表面活性剂的两步电沉积方法成功合成了清晰的氧化铜纳米线(CuO NWs)结构。使用场发射扫描电子显微镜(FESEM)和X射线光电子能谱(XPS)研究获得的CuO NW。通过循环伏安法和计时电流法研究了碱性条件下CuO NWs修饰的玻璃碳(CuO NWs / GC)电极对非酶法检测葡萄糖(Glc)的电化学性能。观察到CuO NWs对Glc具有优异的电还原活性。 CuO NWs / GC传感器的特征是:Glc(0.0125-4.29 mM)的线性范围宽,灵敏度高(759.86μAmM?1cm?2),响应时间短(4s)和检测下限(LOD = 4.17μM) )。此外,该传感器具有良好的重现性,抗干扰能力和长期稳定性。因此,它暗示了CuO NWs / GC作为非酶检测和定量葡萄糖的传感器的潜在适用性。

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