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Synthesis and Electrochemical Studies of Some Metal Complexes with Phosphorus Schiff Base Ligand

机译:磷席夫碱配体的某些金属配合物的合成及电化学研究

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The complexes of type [CrLCl]0.5H2O and [ML(H2O)]nH2O in which M = Co(II); n = 4.5, Ni(II); n =4.5, Cu(II); n = 7 and Zn(II); n = 6.5 ions and L is N,N'- bis(2扝ydroxybenzylidene),1抎iaminomethylphosphine-oxide, were prepared and their structures1 31 characterized by elemental analysis, IR, H NMR, P NMR, XRD, GA, CV, mass, molar conductance,magnetic moment and UVisible spectra. Antimicrobial activities have been studied using the agar- disc diffusion technique, and the higher antimicrobial activity has been observed for the chromium(III)complex compared to the other metal complexes. The redox behavior of complexes was investigatedby cyclic voltammetry.
机译:[CrLCl] 0.5H2O和[ML(H2O)] nH2O类型的配合物,其中M = Co(II); n = 4.5,Ni(II); n = 4.5,铜(II); n = 7和Zn(II);制备了n = 6.5个离子,L为N,N'-双(2-扝氧基苄基亚甲基),1-抎氨基甲基膦氧化物,并通过元素分析,IR,H NMR,P NMR,XRD,GA,CV对其结构进行了表征1 31质量,摩尔电导,磁矩和紫外光谱。已经使用琼脂盘扩散技术研究了抗菌活性,与其他金属配合物相比,铬(III)配合物的抗菌活性更高。通过循环伏安法研究了配合物的氧化还原行为。

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