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Electroplating in Steel in Presence of Isopropanol-Water Mixture

机译:异丙醇-水混合物中钢的电镀

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The rate of electroplating of steel in acidified CuSO4 solution in absence and presence of isopropanolalcohol were studied by measuring the limiting current. It found that the rate of electroplating wasdecreased in presence of alcohol. The rate of inhibition rang from 40% to 66% depending on theconcentration of alcohol. Thermodynamic properties Ea, H*, S*and G* were calculated. The value-1 of Ea < 42 kJ mol.l , which indicate that, reaction, is diffusion controlled.
机译:通过测量极限电流,研究了在不存在和存在异丙醇的条件下,钢在酸性CuSO4溶液中的电镀速率。发现在酒精存在下电镀速率降低。抑制率从40%到66%不等,取决于酒精的浓度。计算了热力学性质Ea,H *,S *和G *。 Ea的值-1 <42 kJ mol.l,表明反应受扩散控制。

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