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A Green Synthesis of Mn3O4/graphene Nanocomposite as Anode Material for Lithium-Ion Batteries

机译:Mn 3 O 4 /石墨烯纳米复合材料的绿色合成作为锂离子电池的负极材料

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A green and gentle synthesis method of Mn3O4/graphene nanocomposite is supplied to achieve a high property anode material for Li-ion batteries. The synthesis process of Mn3O4/graphene nanocomposites consists of two parts: one is the formation of Mn3O4 nanoparticles by hydrothermal reaction; the other is the reduction of graphene oxide to graphene by Vitamin C in hot bath, companied with the combination of graphene and Mn3O4. During the preparation process, all raw materials and by- products are non-toxic, meanwhile, the methods are green, gentle and energy saving. The resulting materials are characterized by XRD, SEM and TG. The composite materials deliver a stable reversible capacity of 500 mA h g-1 at a current density of 100 mA g-1 even after 100 cycles. The reversible capacity of the samples coated by crumpled graphene is higher than pure Mn3O4 nanoparticles. This research supplies a new effective strategy to fabricate metal oxide/graphene nanocomposites with high electrochemical performances anode materials through a real environmental friendly method.
机译:提供了一种绿色温和的Mn3O4 /石墨烯纳米复合材料合成方法,以实现用于锂离子电池的高性能负极材料。 Mn3O4 /石墨烯纳米复合材料的合成过程由两部分组成:一是通过水热反应生成Mn3O4纳米颗粒。另一种是在热浴中,维生素C与石墨烯和Mn3O4的组合,将氧化石墨烯还原为石墨烯。在制备过程中,所有原料和副产品均无毒,同时,该方法绿色环保,温和节能。所得材料通过XRD,SEM和TG表征。即使在100次循环后,复合材料在100 mA g-1的电流密度下仍具有500 mA h g-1的稳定可逆容量。皱纹石墨烯涂层样品的可逆容量高于纯Mn3O4纳米颗粒。这项研究提供了一种新的有效策略,通过一种真正的环保方法来制造具有高电化学性能的阳极材料的金属氧化物/石墨烯纳米复合材料。

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