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首页> 外文期刊>International Journal of Electrochemical Science >Surfactant Effect as Template Agent on the Morphological and Electrochemical Properties of V2O5
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Surfactant Effect as Template Agent on the Morphological and Electrochemical Properties of V2O5

机译：表面活性剂作为模板剂对V 2 O 5 的形态和电化学性质的影响

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The effect of the release of cetylpyridinium chloride surfactant into the V2O5 following the behavior oflithium intercalation into an electrode containing the V2O5 film has been investigated. X-raydiffraction patterns indicated formation of a lamellar structure. After the calcination and release ofsurfactant occurred the formation of an orthorhombic structure. Scanning Electronic Microscopyshows that the route employed for the preparation of an open network V2O5 structure was successful.The electrochemical performance of the open network structured material compared with a compactstructure of V2O5, via sol-gel route as lithium intercalation cathode materials were evaluated. The opennetwork material reaches stability more easily and presents a high total voltammetric charge afterseveral cycles compared with the V2O5 xerogel. Lithium intercalation into the V2O5 electrode is veryinfluenced by open network surface and surface irregularity, in contrast with the compact surface ofthe V2O5 xerogel.
机译：研究了将十六烷基吡啶鎓氯化物表面活性剂释放到V2O5中的行为，这种行为是由于锂嵌入到包含V2O5膜的电极中而引起的。 X射线衍射图样表明形成了层状结构。煅烧和释放表面活性剂后，形成了正交晶结构。扫描电子显微镜显示成功制备了开放网络的V2O5结构的途径。评价了开放网络结构的材料与V2O5的致密结构相比，通过溶胶-凝胶法作为锂嵌入阴极材料的电化学性能。与V2O5干凝胶相比，开放网络材料更容易达到稳定性，并在多个循环后呈现出较高的总伏安电荷。与V2O5干凝胶的致密表面相比，锂嵌入V2O5电极中的情况受开放的网络表面和表面不规则性的影响很大。

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