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Synthesis and Characterization of Graphene/Polythiophene (GR/PT) Nanocomposites: Evaluation as High-Performance Supercapacitor Electrodes

机译:石墨烯/聚噻吩(GR / PT)纳米复合材料的合成和表征:作为高性能超级电容器电极的评估

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Composites of polythiophene (PT) and graphene (GR) with different mass proportions were studied for their application as supercapacitors. Fourier transform infrared spectroscopy (FTIR) along with High Resolution Scanning electron microscopy (HR-SEM) were employed in order to characterize the morphology and composition of the resulting composites. The electrochemical behaviour of these composites was studied by means of cyclic voltammetry and specific capacitance curves were derived from these measurements. The Faradaic impedance spectroscopy response of the different composites, along with that of GR, was also studied. From these measurements it was found that a 1:1 in mass composite of GR and PT showed a higher specific capacitance, even when compared with GR alone. The introduction of the GR in that proportion also showed an enhanced cyclic stability in comparison with the sole polymer. The high specific capacitance (365 F g?1 at 1 A g-1) of this composite material indicates its potential for use as an electrode material for supercapacitors.
机译:研究了不同质量比的聚噻吩(PT)和石墨烯(GR)的复合材料作为超级电容器的应用。为了表征所得复合材料的形态和组成,采用了傅里叶变换红外光谱(FTIR)和高分辨率扫描电子显微镜(HR-SEM)。通过循环伏安法研究了这些复合材料的电化学行为,并从这些测量值得出了比电容曲线。还研究了不同复合材料以及GR的法拉第阻抗谱响应。从这些测量结果中发现,即使与单独的GR相比,GR和PT的质量比为1:1的复合材料也显示出更高的比电容。与单一聚合物相比,以该比例引入GR还显示出增强的循环稳定性。这种复合材料的高比电容(在1 A g-1时为365 F g?1)表明其用作超级电容器电极材料的潜力。

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