• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>International Journal of Electrochemical Science >Heteroatom-enhanced the Formation of Mesoporous Carbon Microspheres with High Surface Area as Supercapacitor Electrode Materials
【24h】

Heteroatom-enhanced the Formation of Mesoporous Carbon Microspheres with High Surface Area as Supercapacitor Electrode Materials

机译：杂原子增强了高表面积介孔碳微球作为超级电容器电极材料的形成

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A novel supercapacitor electrode material based on heteroatom (N, O, P) doped mesoporous carbon microspheres (HMCMSs) was produced via a carbonization of highly cross-linked polyphosphazene microspheres (PMSs), with N, O, P acting as high efficient pore-forming agent. PMSs were synthesized through the polymerization reaction between melamine (MA) and hexachlorocyclotriphosphazene (HCCP). The high level of heteroatom atom of PMSs effectively afforde HMCMSs with high specific surface area (1854.1m2/g), united mesopore structure (pore width ~3nm), as well as high supercapacitor performance. HMCMSs based electrodes exhibited highest specific capacitance of 274 F/g in 6 M KOH aqueous electrolyte at a current density of 0.2 A/g, and excellent cycling durability which had 98.4% capacitance retained even after 2000 cycles. These animative consequences of HMCMSs based electrodes show them great potential in developing high- performance supercapacitors for actual application.
机译：通过对高度交联的聚磷腈微球（PMS）进行碳化，制备了一种基于杂原子（N，O，P）掺杂的介孔碳微球（HMCMS）的新型超级电容器电极材料，其中N，O，P充当了高效的形成剂。通过三聚氰胺（MA）和六氯环三磷腈（HCCP）之间的聚合反应合成了PMS。 PMS的高杂原子水平有效地提供了具有高比表面积（1854.1m2 / g），统一的中孔结构（孔宽〜3nm）以及高超级电容器性能的HMCMS。基于HMCMSs的电极在电流密度为0.2 A / g的6 M KOH水溶液中显示出最高的比电容为274 F / g，并且具有出色的循环耐久性，即使在2000次循环后仍保持了98.4％的电容。基于HMCMS的电极的这些动画效果显示出它们在为实际应用开发高性能超级电容器方面的巨大潜力。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号