首页> 外文期刊>International Journal of Electrochemical Science >Study on corrosion inhibition of Q235 steel in HCl solution by 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11- diene diperchlorate
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Study on corrosion inhibition of Q235 steel in HCl solution by 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11- diene diperchlorate

机译:5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四烷-4,11-二烯二氯酸盐对Q235钢在HCl溶液中的缓蚀作用研究

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摘要

The corrosion inhibition of Q235 steel in HCl solution by 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraaz- acyclotetradeca-4,11-diene diperchlorate (HMTADE-2HClO4) has been studied using potentiodynamic polarization, weight loss measurement and microstructure analysis. Measurements results suggest that HMTADE-2HClO4 is an effective mixed-type inhibitor, the inhibition efficiency increase with HMTADE-2HClO4 concentration increasing, decrease with temperature and HCl concentration increasing, and slightly fluctuate with storage time changing. The experimental results are further suggest that the adsorption of HMTADE-2HClO4 on Q235 steel surface obeys Langmuir isotherm, which is a mixed adsorption involving both physisorption and chemisorption.
机译:研究了5,7,7,12,14,14-六甲基-1,4,8,11-四唑-无环十四烷基-4,11-二烯二氯酸盐(HMTADE-2HClO4)对Q235钢在HCl溶液中的腐蚀抑制作用使用电位动力学极化,失重测量和微观结构分析。测量结果表明,HMTADE-2HClO4是一种有效的混合型抑制剂,其抑制效率随HMTADE-2HClO4浓度的增加而增加,随温度和HCl浓度的增加而降低,随贮存时间的变化而略有波动。实验结果进一步表明,HMTADE-2HClO4在Q235钢表面的吸附遵循Langmuir等温线,这是一种既涉及物理吸附又涉及化学吸附的混合吸附。

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