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In situ Corrosion Study of Copper and Copper-Alloys Exposed to Natural Seawater of the Veracruz Port (Gulf of Mexico)

机译:韦拉克鲁斯港口(墨西哥湾)的天然海水中暴露的铜和铜合金的原位腐蚀研究

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In this study, the effect of seasonal variability on the marine environment in the corrosion of Cu and Cu-Alloys was analyzed in situ with respect to exposure time. The possible changes in the mechanism of degradation, considering the physicochemical parameters of seawater were studied. An electrochemical study was carried out with three metallic materials industrially used (copper, bronze and brass) for 10 months of continuous exposure in seawater surrounding the San Juan de Ulua Fortress in Veracruz port, Mexico. Electrochemical impedance spectroscopy (EIS) was the electrochemical technique used. Additionally, a characterization of the metal surface with scanning electron microscopy (SEM) and X-ray diffraction (XRD) was carried out. All materials showed good corrosion resistances; however, copper showed higher resistance which took their best values in the last months of exposure presenting a layer of products of Cu2O. Additionally, some silicates and sulfates were detected. Pitting and localized corrosion type was observed.
机译:在这项研究中,就暴露时间而言,就地分析了铜和铜合金腐蚀中季节性变化对海洋环境的影响。考虑到海水的理化参数,研究了降解机理的可能变化。在墨西哥韦拉克鲁斯港口的San Juan de Ulua堡垒周围的海水中,对三种工业用金属材料(铜,青铜和黄铜)进行了连续10个月的电化学研究。电化学阻抗谱(EIS)是所使用的电化学技术。另外,利用扫描电子显微镜(SEM)和X射线衍射(XRD)对金属表面进行表征。所有材料均显示出良好的耐腐蚀性;但是,铜表现出更高的电阻,在暴露的最后几个月中表现出最佳值,呈现出一层Cu2O产品。此外,还检测到一些硅酸盐和硫酸盐。观察到点蚀和局部腐蚀类型。

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