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Synthesis of Novel Azophenylbenzotriazole and Its Application as Anode Materials for Lithium Ion Batteries

机译:新型偶氮苯基苯并三唑的合成及其在锂离子电池负极材料中的应用

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The substitution of renewable organic electrodes for environmentally unfriendly inorganic electrodes isa pivotal link in the development of lithium-ion batteries (LiBs) for large-scale energy storage. Here,we report a new type of organic electrode material based on azophenyl and benzotriazolyl (BTA)groups for LiBs. In view of the easy formation of Cu-BTA complexes in the interface of the coppercurrent collector of LiBs anode, we synthesized azophenylalkylbenzotriazoles, and studied theirelectrochemical behavior and reaction mechanism as organic electrode materials in LiBs. Thesynthesized azophenylalkylbenzotriazoles showed the high reversible capacity up to 365.8 mAhg -1 at25 mAg -1 of current density.
机译:用可再生有机电极代替对环境不友好的无机电极是锂离子电池(LiBs)大规模储能开发中的关键环节。在这里,我们报告一种新型的基于LiBs的偶氮苯基和苯并三唑基(BTA)基团的有机电极材料。鉴于在LiBs阳极的铜集流体的界面上容易形成Cu-BTA络合物,我们合成了偶氮苯基烷基苯并三唑,并研究了它们作为LiBs有机电极材料的电化学行为和反应机理。合成的偶氮苯基烷基苯并三唑在25 mAg -1的电流密度下显示出高达365.8 mAhg -1的高可逆容量。

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