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Supercapacitor Nanofiber Electrodes Graphene-Based

机译:基于石墨烯的超级电容器纳米纤维电极

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Carbon-based polyacrylonitrile (PAN) nanofiber mats formed via the electrospinning process with varying amounts of graphene and carbon black were used as electrodes in single cell supercapacitor experiments in 1M H2SO4. A strong influence of initial electrospinning mixture concentration on capacitance and electrode structure was observed. Electrodes fabricated from a lower carbon mixture containing PAN and graphene showed the highest capacitances whereas electrodes fabricated from higher carbon mixtures of PAN, graphene and carbon black had significantly lower capacitance values. Transmission electron microscope (TEM) images show an amorphous carbon structure for electrodes with the highest capacitance value whereas a turbostratic structure was more prevalent for the lower capacitance supercapacitors.
机译:在1M H2SO4中的单电池超级电容器实验中,将通过电纺丝工艺形成的碳基聚丙烯腈(PAN)纳米纤维毡与不同数量的石墨烯和炭黑一起用作电极。观察到初始电纺丝混合物浓度对电容和电极结构的强烈影响。由包含PAN和石墨烯的低碳混合物制成的电极显示最高的电容,而由PAN,石墨烯和炭黑的较高碳混合物制成的电极具有明显较低的电容值。透射电子显微镜(TEM)图像显示出具有最高电容值的电极的非晶碳结构,而对于较低电容的超级电容器,涡轮层结构更为普遍。

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