首页> 外文期刊>International Journal of Electrochemical Science >Study on the Corrosion Inhibition Effect of 2,3-Dimercapto-1- propanol on Copper in 0.5mol/L H2SO4 Solution
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Study on the Corrosion Inhibition Effect of 2,3-Dimercapto-1- propanol on Copper in 0.5mol/L H2SO4 Solution

机译:2,3-二巯基-1-丙醇在0.5mol / L H 2 SO 4 溶液中对铜的缓蚀作用研究

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In this paper, the inhibition performance of 2,3-Dimercapto-1-propanol (DIP) in 0.5 M sulfuric acidwere studied by polarization curves, impedance spectroscopy, scanning electron microscopy, atomicforce microscopy and theoretical calculations. The results of electrochemical experiments manifest thatDIP is a cathode corrosion inhibitor that can produce a compact protective membrane on the surface ofcopper, which can effectively reducing the corrosion current density. Field emission scanning electronmicroscope (FE-SEM) and atomic force microscopy (AFM) certificated that a conservationalmembrane was produced on the surface of the inhibited sample. In addition, the adsorption of theinhibitor was found to be consistent with the Langmuir isotherm. Molecular dynamics simulations andquantum chemical calculations were applied to elucidate the adsorption mode of inhibitor moleculeson copper surfaces.
机译:本文通过极化曲线,阻抗谱,扫描电镜,原子力显微镜和理论计算研究了2,3-二巯基-1-丙醇(DIP)在0.5 M硫酸中的缓蚀性能。电化学实验结果表明,DIP是一种阴极缓蚀剂,可以在铜表面形成致密的保护膜,可以有效降低腐蚀电流密度。场发射扫描电子显微镜(FE-SEM)和原子力显微镜(AFM)证明,在被抑制样品的表面上产生了保护膜。另外,发现抑制剂的吸附与朗缪尔等温线一致。应用分子动力学模拟和量子化学计算来阐明抑制剂分子在铜表面的吸附方式。

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