Electrooxidation of Phenol at Palladium-Based Catalyst Materials in Alkaline Solution

Boguslaw Pierozynski; Tomasz Mikolajczyk; Grazyna Piotrowska

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Electrooxidation of Phenol at Palladium-Based Catalyst Materials in Alkaline Solution

机译：碱溶液中钯基催化剂上苯酚的电氧化

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This paper reports on kinetics of phenol electrooxidation reaction (PhER), examined on large surfacearea Pd-modified nickel foam electrode and comparatively on Pd wire surface in 0.1 M NaOHsupporting electrolyte. The kinetics of PhER were monitored through potential-dependent, a.c.impedance-recorded values of charge-transfer resistance and capacitance parameters, also in relation toan important step of phenol molecule electrosorption on the catalyst surface.

机译：本文报道了酚电氧化反应（PhER）的动力学，在大表面积的Pd改性镍泡沫电极上以及在0.1 M NaOH支持的电解质中的Pd丝表面上进行了比较。 PhER的动力学是通过电势相关的，电荷记录的电荷转移电阻和电容参数的阻抗记录值来监控的，这也与酚分子在催化剂表面的电吸附的重要步骤有关。

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《International Journal of Electrochemical Science》 |2015年第3期|共10页
作者
Boguslaw Pierozynski; Tomasz Mikolajczyk; Grazyna Piotrowska;
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Electrooxidation of Phenol at Palladium-Based Catalyst Materials in Alkaline Solution

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