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首页> 外文期刊>International Journal of Electrochemical Science >Corrosion Performance of Nanostructured Clay Hybrid Film based on Crosslinked 3-(Acrylamidopropyl) Trimethylammonium Chloride –co- Acrylamide on Mild Steel in Acidic Medium
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Corrosion Performance of Nanostructured Clay Hybrid Film based on Crosslinked 3-(Acrylamidopropyl) Trimethylammonium Chloride –co- Acrylamide on Mild Steel in Acidic Medium

机译：交联的3-（丙烯酰胺基丙基）三甲基氯化铵-共丙烯酰胺纳米结构粘土杂化膜在酸性介质中对低碳钢的腐蚀性能

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The present work describes the exfoliation of clay through crosslinking with 3- (acrylamidopropyl)trimethylammonium chlorideo- acrylamide (APTAC/AM) which made the polymer end-tethered onNa-MMT. However, the way in which APTAC/AM interacts with the surface of MMT has not yetbeen studied. APTAC/AM widened the gap between clay layers and facilitates comonomers penetrateinto clay. The exfoliated structure of extracted nanocomposite was confirmed by Fourier transforminfrared (FTIR), X-ray powder diffraction XRD, thermogravimetric analyses (TGA) and transmissionelectron microscopy (TEM). Results of FT-IR, TGA and XRD analyses showed that APTAC/AMinteracted with clay, but to various extents. The inhibition effect of APTAC/AM-MMT on thecorrosion of steel in 1.0 M HCl solution was studied by potentiodynamic polarization curves andelectrochemical impedance spectroscopy (EIS) methods. All electrochemical measurements indicatethat APTAC/AM-MMT functioned as a good inhibitor in 1M hydrochloric solution and inhibitionefficiency increased with APTAC/AM-MMT concentration. Polarization curves indicate thatAPTAC/AM-MMT acts as mixed-type inhibitor. EIS spectra exhibit one capacitive loop. The chargetransfer resistance (Rct) increases with APTAC/AM-MMT concentration, while double layercapacitance (Cdl) decreases.
机译：本工作描述了通过与3-（丙烯酰胺基丙基）三甲基氯化铵-丙烯酰胺（APTAC / AM）交联来剥离粘土的方法，该方法使聚合物端接在Na-MMT上。但是，尚未研究APTAC / AM与MMT表面相互作用的方式。 APTAC / AM拓宽了粘土层之间的间隙，并有助于共聚单体渗入粘土。通过傅立叶变换红外（FTIR），X射线粉末衍射XRD，热重分析（TGA）和透射电子显微镜（TEM）确认提取的纳米复合材料的剥离结构。 FT-IR，TGA和XRD分析结果表明APTAC / AM与粘土相互作用，但程度不同。通过电位动力学极化曲线和电化学阻抗谱（EIS）方法研究了APTAC / AM-MMT对1.0 M HCl溶液中钢的缓蚀作用。所有电化学测量表明，APTAC / AM-MMT在1M盐酸溶液中起良好的抑制剂作用，并且随着APTAC / AM-MMT浓度的增加，抑制效率也随之提高。极化曲线表明，APTAC / AM-MMT充当混合型抑制剂。 EIS光谱显示出一个电容环路。电荷转移电阻（Rct）随着APTAC / AM-MMT浓度的增加而增加，而双层电容（Cdl）则降低。

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