Abrasive Voltammetry of Trinuclear Cobalt-Benzoato Complex with iso-Nicotinamide at a Carbon Paste Electrode

Juraj Hudák; Tomá? Mikysek; Roman Boca; Karel Vytras

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Abrasive Voltammetry of Trinuclear Cobalt-Benzoato Complex with iso-Nicotinamide at a Carbon Paste Electrode

机译：碳糊电极上三异钴胺与异烟酰胺的三伏钴-苯甲酰络合物的研磨伏安法

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A voltammetric study of [Co3(-bz)4(bz)2(inca)2] complex (insoluble in aqueous media) using carbonpaste electrode is presented. The electrochemical behaviour of the complex was investigated in variousmedia (sodium hydroxide, sulphuric acid and perchloric acid). In acidic media a reduction of iso- nicotinamide ligand was observed whereas in alkaline media a reversible oxidation of its Co(II) centreoccurs.

机译：提出了使用碳膏电极对[Co3（-bz）4（bz）2（inca）2]配合物（不溶于水介质）进行伏安研究。在各种介质（氢氧化钠，硫酸和高氯酸）中研究了配合物的电化学行为。在酸性介质中，观察到异烟酰胺配体的还原，而在碱性介质中，其Co（II）中心发生可逆氧化。

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《International Journal of Electrochemical Science》 |2013年第4期|共5页
作者
Juraj Hudák; Tomá? Mikysek; Roman Boca; Karel Vytras;
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Abrasive Voltammetry of Trinuclear Cobalt-Benzoato Complex with iso-Nicotinamide at a Carbon Paste Electrode

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