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Facile Synthesis of Cobalt Vanadium Oxides and Their Applications in Lithium Batteries

机译:钴钒氧化物的简便合成及其在锂电池中的应用

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Cobalt vanadium oxides (CoV2O6 and Co2V2O7) have been one-step synthesized by a soft chemistryroute without any templates. The as-prepared materials were characterized by a variety of analyticaltechniques, including X-ray diffraction (XRD), Scanning electron microscopy (SEM), Energydispersive X-ray spectroscopy (EDS), Fourier-transform infrared spectroscopy (FT-IR). The XRDpatterns showed that the as-prepared materials are of high crystallinity and high purity. The SEMimages showed that the Co2V2O7 material is very uniform and well-separated, with diameters around 1um. The electrochemical performances were also investigated and the results show that the CoV2O6-1 material can deliver a high initial discharge capacity of 1243 mAh g at the current density of 20 mA-1 -1g and the Co2V2O7 material exhibits a high initial discharge capacity of 949 mAh g even at a large-1 current density as high as 500 mA g .
机译:钴钒氧化物(CoV2O6和Co2V2O7)已通过无任何模板的软化学路线一步合成。所制备的材料具有多种分析技术的特征,包括X射线衍射(XRD),扫描电子显微镜(SEM),能量色散X射线光谱(EDS),傅里叶变换红外光谱(FT-IR)。 XRD图谱表明,所制备的材料具有高结晶度和高纯度。 SEM图像显示Co2V2O7材料非常均匀且分离良好,直径约为1um。还研究了电化学性能,结果表明,CoV2O6-1材料在20 mA-1 -1g的电流密度下可提供1243 mAh g的高初始放电容量,而Co2V2O7材料则具有949的高初始放电容量甚至在大电流密度高达500 mA g的情况下mAh g。

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