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Anatase TiO2 Hollow Nanospheres with Ultrathin Shell Exhibit Superior Lithium Storage Property

机译:具有超薄壳的锐钛矿型TiO 2 空心纳米球表现出优异的锂存储性能

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TiO2 hollow nanospheres with ultrathin shell of ca.10 nm were prepared by using sulfur nanospheresas templates and its electrochemical performance was investigated as anode material for lithium ionbattery. The results show that the as-obtained anatase TiO2 exhibits superior lithium storage capabilitydue to its characteristic lithium storage mechanism and somewhat pseudocapacitive property. The as- -1 obtained anatase TiO2 electrode delivered a high initial specific capacity of 574.5 mAh g at 168 mA-1 g and displays excellent cycling performance after first cycle, which might be attributed to theimprovement of ionic and electron conduction of anatase TiO2 due to the unique hollow nanostructurewith ultrathin shell.
机译:以硫纳米球为模板制备了超薄壳约10nm的TiO2空心纳米球,并研究了其电化学性能作为锂离子电池的负极材料。结果表明,所获得的锐钛矿型TiO2由于其独特的锂存储机理和一定的拟电容特性而具有优异的锂存储能力。 as- -1获得的锐钛矿型TiO2电极在168 mA-1 g时具有574.5 mAh g的高初始比容量,并且在第一个循环后显示出优异的循环性能,这可能归因于锐钛型TiO2的离子和电子导电性的提高。具有超薄外壳的独特中空纳米结构。

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