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Corrosion of Aluminium in Concentrated LiNO3 Solution at High Temperature

机译:铝在高温LiNO 3 浓溶液中的腐蚀

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The corrosion of aluminium in concentrated LiNO3 solution at high temperature was studied with aweight loss method. The effects of concentration, temperature, pH and Li2CrO4 on corrosion rates wereinvestigated. Results indicated that increasing concentration of LiNO3 had opponent effects onaluminium corrosion. Elevating temperature and pH could increase the corrosion rate. An incompacthydroxide film was observed on the surface of aluminium in LiNO3 solution. The corrosion waseffectively depressed by adding inhibitor Li2CrO4, where a compact passive film comprising Al(OH)3and Cr2O3 may be formed. The corrosion rate of aluminium in LiNO3 solution was much smaller thanthat in LiBr solution.
机译:采用失重法研究了铝在浓LiNO3溶液中的高温腐蚀行为。研究了浓度,温度,pH和Li2CrO4对腐蚀速率的影响。结果表明,LiNO3浓度的增加对铝的腐蚀有相反的影响。升高温度和pH值可能会增加腐蚀速率。在LiNO3溶液中的铝表面上观察到不完整的氢氧化物膜。通过加入抑制剂Li2CrO4可以有效地抑制腐蚀,在其中可以形成包含Al(OH)3和Cr2O3的致密钝化膜。 LiNO3溶液中铝的腐蚀速率远小于LiBr溶液中的铝。

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