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Phase Equilibrium between CaO·Al2O3 Saturated Molten CaO–Al2O3–MnO and (Ca, Mn)S Solid Solution

机译:CaO·Al 2 O 3 饱和熔融CaO–Al 2 O 3 –MnO与(Ca的相平衡,Mn)S固溶体

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Refinement of austenite grains by generating intra granular ferrite (IGF) in austenite grains is one of the most effective methods for improving the toughness of the heat-affected zone (HAZ). It is known that MnS precipitated on fine oxides enhance formation of IGF in austenite grains. Flux composed of CaO–Al_(2)O_(3) is often used in secondary refining and Ca–Mn–Al complex oxide may form, and it is important to clarify the mechanism of MnS precipitation on oxide inclusions. Therefore, molten CaO–MnO–Al_(2)O_(3) oxide was equilibrated with (Ca, Mn)S solid solution in Al_(2)O_(3) crucible in an electric resistance furnace at 1648, 1698 and 1748 K in the present work. Phase relation between CaO·Al_(2)O_(3) saturated molten CaO–MnO–Al_(2)O_(3) oxide and (Ca, Mn)S solid solution was clarified.
机译:通过在奥氏体晶粒中生成内部颗粒铁素体(IGF)来细化奥氏体晶粒是提高热影响区(HAZ)韧性的最有效方法之一。已知在细氧化物上沉淀的MnS会增强奥氏体晶粒中IGF的形成。由CaO–Al_(2)O_(3)组成的助焊剂通常用于二次精炼,并且可能形成Ca–Mn–Al复合氧化物,因此阐明MnS沉淀在氧化物夹杂物上的机理非常重要。因此,用电阻炉中的Al_(2)O_(3)坩埚在1648、1698和1748 K的温度下用(Ca,Mn)S固溶体平衡熔融的CaO–MnO–Al_(2)O_(3)氧化物。目前的工作。阐明了CaO·Al_(2)O_(3)饱和熔融CaO–MnO–Al_(2)O_(3)氧化物与(Ca,Mn)S固溶体之间的相位关系。

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