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Wettability of Al2O3, MgO and Ti2O3 by Liquid Iron and Steel

机译:钢铁对Al 2 O 3 ,MgO和Ti 2 O 3 的润湿性

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The wetting behavior of liquid iron and steel on Al_(2)O_(3), MgO and Ti_(2)O_(3) substrates was measured by using the sessile drop method. Measurements were carried out using a controlled oxygen partial pressure and using an argon protected atmosphere. For the Al_(2)O_(3) and MgO substrates, reaction layers in form of FeAl_(2)O_(4) and MgO–FeO (solid solution) were formed. These layers slightly decreased the contact angle and surface tension values after a full melting. For a Ti_(2)O_(3) substrate in contact with pure Fe, no-reaction could be observed at the interface. Furthermore, the contact angle and surface tension values were almost stable after a full melting. For a Ti_(2)O_(3) substrate in contact with steel, the contact angle and surface tension values decreased steeply after a full melting, due to the formation Al_(2)TiO_(5) reaction layer formation at the interface.
机译:采用无滴法测定了钢铁在Al_(2)O_(3),MgO和Ti_(2)O_(3)基材上的润湿行为。使用受控的氧分压和氩气保护气氛进行测量。对于Al_(2)O_(3)和MgO衬底,形成了FeAl_(2)O_(4)和MgO–FeO(固溶体)形式的反应层。这些层在完全熔化后会稍微降低接触角和表面张力值。对于与纯Fe接触的Ti_(2)O_(3)衬底,在界面处未观察到任何反应。此外,完全熔化后的接触角和表面张力值几乎稳定。对于与钢接触的Ti_(2)O_(3)衬底,由于在界面处形成了Al_(2)TiO_(5)反应层,因此在完全熔化后接触角和表面张力值急剧下降。

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