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首页> 外文期刊>ISIJ international >Influence of Surface Modification on Combustion Characteristics of Charcoal and Its Performance on Emissions Reduction in Iron Ore Sintering
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Influence of Surface Modification on Combustion Characteristics of Charcoal and Its Performance on Emissions Reduction in Iron Ore Sintering

机译:表面改性对木炭燃烧特性的影响及其对降低铁矿石烧结排放的性能

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For bridging the huge gap of combustibility between coke breeze and charcoal in iron ore sintering, the influences of using SiO_(2) and B_(2)O_(3) as modifiers on combustion characteristics of charcoal were investigated. The results showed that due to the physical barrier function of SiO_(2) powders and the surface covering function of B_(2)O_(3) film, the porosity of modified charcoal was reduced. The combustion speed of modified charcoal was therefore slowed down and showed less differences to coke breeze than non-modified charcoal. Recommended mass percentages of SiO_(2) and B_(2)O_(3) in modified charcoal were 2% and 3% respectively. The combustion reaction activation energy of charcoal was increased from 55.54 kJ?mol~(?1) to 86.97 kJ?mol~(?1) and 92.82 kJ?mol~(?1) respectively after modification, which was close to 122.75 kJ?mol~(?1) of coke breeze. Laboratory-scale sintering tests showed that the proper replacement percentage of charcoal to coke breeze was increased from 20% to 40% after the surface modification. And the emission reduction percentages of NOx and SOx were correspondingly improved from 16.58% and 11.02% to about 28% and 37% respectively, while the average combustion efficiency was kept at the comparable level to the case using coke breeze only.
机译:为了弥合铁矿石烧结过程中焦风与木炭之间巨大的可燃性差距,研究了使用SiO_(2)和B_(2)O_(3)作为改性剂对木炭燃烧特性的影响。结果表明,由于SiO_(2)粉体的物理阻挡作用和B_(2)O_(3)膜的表面覆盖作用,改性木炭的孔隙率降低。因此,与未改性的木炭相比,改性木炭的燃烧速度减慢并且与微风的差异较小。改性木炭中SiO_(2)和B_(2)O_(3)的推荐质量百分比分别为2%和3%。改性后,木炭的燃烧反应活化能分别从55.54 kJ?mol〜(?1)增加到86.97 kJ?mol〜(?1)和92.82 kJ?mol〜(?1),接近122.75 kJ?mol〜(?1)。 mol〜(?1)轻风。实验室规模的烧结测试表明,表面改性后,木炭对微风的适当替代百分比从20%增加到40%。 NOx和SOx的排放减少百分比分别从16.58%和11.02%分别提高到约28%和37%,同时平均燃烧效率保持与仅使用焦风的情况相当。

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