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Synthesis of Calcium Ferrite from Waste Gypsum Board

机译:废石膏板合成铁酸钙

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Herein, we investigate the chemical recycling of waste gypsum board obtaining synthetic calcium ferrite for making steel. Thermodynamic estimation and results of small-scale heating tests revealed that decomposition of gypsum was promoted in the partial pressure of O_(2) and lower partial pressure of SO_(2) by preventing the formation of CaS. The addition of Fe_(2)O_(3) to gypsum helped reduce the decomposition temperature of gypsum, resulting in formation of calcium ferrite in a lower temperature. Decomposition of gypsum was incomplete after heating in air at 1180°C, whereas calcium ferrite was successfully obtained by a two-step heat treatment of gypsum: forming CaS through carbon reduction and heating the fine mixture of Fe_(2)O_(3) and CaS at 1180°C. Calcium ferrite can also be obtained in a single heat treatment if we use the proper gas and material conditions. After trial tests using a large-scale rotary kiln, we confirmed that heating a sample containing gypsum, coke fine, and Fe_(2)O_(3) at a temperature less than 1200°C resulted in the formation of calcium ferrite accompanied with a high desulfurization degree of gypsum.
机译:在本文中,我们研究了废石膏板的化学回收利用,从而获得了用于制造钢的合成铁酸钙。热力学估计和小规模加热试验的结果表明,通过阻止CaS的形成,石膏的分解在O_(2)的分压和SO_(2)的较低分压中得到了促进。在石膏中添加Fe_(2)O_(3)有助于降低石膏的分解温度,从而在较低的温度下形成铁酸钙。在空气中于1180°C加热后,石膏的分解不完全,而石膏的两步热处理成功地获得了铁素体钙:通过碳还原形成CaS并加热Fe_(2)O_(3)和CaS在1180°C下。如果我们使用适当的气体和材料条件,也可以通过一次热处理获得铁酸钙。经过使用大型回转窑的试验测试,我们确认了在低于1200°C的温度下加热包含石膏,焦炭细粉和Fe_(2)O_(3)的样品会导致形成铁酸钙并伴随着石膏的高脱硫率。

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