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Electrical conductivity measurements of brucite under crustal pressure and temperature conditions

机译:在地壳压力和温度条件下水镁石的电导率测量

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Hydrous minerals are crucial because their occurrence is associated with seismic activity through the dehydration process that occurs in the earth's crust and/or mantle. We have developed a technique to observe the dehydration reaction of brucite using electrical conductivity variation under sealed conditions. The electrical conductivity of brucite was measured as a function of temperature. The confining pressure for the measurements was 1 GPa, which represents that of the lower crust. Two types of remarkable electrical conductivity variation were observed. During the first heating, the conductivity of the sample showed a linear variation below 700 K, as was expected from the Arrhenius equation. Once the temperature was increased to near the dehydration boundary, the sample showed a high conductivity. Even though only a small amount of H2O was formed after dehydration, bulk conductivity of the sample varied greatly, presumably caused by a combination of the presence of coexisting solid and fluid phases and a mixed electronic and ionic conduction mechanism operating in the sample.
机译:含水矿物至关重要,因为含水矿物的发生与地壳和/或地幔中发生的脱水过程相关的地震活动有关。我们已经开发出一种在密封条件下利用电导率变化观察水镁石脱水反应的技术。测定水镁石的电导率随温度的变化。测量的围压为1 GPa,代表下地壳的围压。观察到两种显着的电导率变化。在第一次加热过程中,样品的电导率显示出低于700 K的线性变化,这是根据Arrhenius方程所预期的。一旦温度升高到脱水边界附近,样品就显示出高电导率。即使在脱水后仅形成少量的H 2 O,样品的整体电导率也变化很大,可能是由于固相和液相共存以及电子和离子混合存在样品中的传导机制。

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