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Evaluation of solid oxide fuel cell anode based on active triple phase boundary length and tortuosity

机译:基于活性三相边界长度和曲折度的固体氧化物燃料电池阳极评估

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An efficient procedure is presented for the evaluation of solid oxide fuel cell (SOFC) anode microstructure triple phase boundary length (TPBL). Triple phase boundary- the one that is common between three phases of the microstructure- has a great influence on the overall efficiency of SOFC because all electrochemical reactions of anode take place in its vicinity. Therefore, evaluation of TPBL for virtual or experimental 3D microstructures is essential for comparison purposes and the optimization processes. In this study, first, an algorithm is proposed to distinguish between percolated and non-percolated clusters for each of the phases. Then, another algorithm is used to determine the value of TPBL for all percolated clusters of three phases. Also, a procedure based on thermal and diffusion analogy is presented to assess the tortuosity of porous and solid phases. Finally for a virtual microstructure, percolated clusters, active and total TPBL and tortuosity are calculated and discussed.
机译:提出了一种有效的程序,用于评估固体氧化物燃料电池(SOFC)阳极微结构三相边界长度(TPBL)。三相边界-微结构的三相之间常见的边界-对SOFC的整体效率有很大的影响,因为阳极的所有电化学反应都在其附近发生。因此,对于虚拟或实验性3D微观结构的TPBL评估对于比较目的和优化过程至关重要。在这项研究中,首先,提出了一种算法来区分每个阶段的渗透和非渗透簇。然后,使用另一种算法来确定三相的所有渗透簇的TPBL值。此外,提出了一种基于热和扩散类比的方法来评估多孔和固相的曲折性。最后,对于虚拟微观结构,计算并讨论了渗透簇,主动和总TPBL和曲折度。

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