Supramolecular Assembly of pH-Sensitive Triphenylene Derived π-Gelators and Their Application as Molecular Template for the Preparation of Silica Nanotubes

Ignacio Mu?oz Resta; Verónica E. Manzano; Florencia Cecchi; Carla C. Spagnuolo; Fabio D. Cukiernik; Pablo H. Di Chenna

首页> 外文期刊>Gels >Supramolecular Assembly of pH-Sensitive Triphenylene Derived π-Gelators and Their Application as Molecular Template for the Preparation of Silica Nanotubes

【24h】

Supramolecular Assembly of pH-Sensitive Triphenylene Derived π-Gelators and Their Application as Molecular Template for the Preparation of Silica Nanotubes

机译：pH敏感的三亚苯基衍生的π-胶凝体的超分子组装及其作为制备硅胶纳米管的分子模板的应用

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The gelation properties and mode of self-assembly of six asymmetrical hexaether triphenylene derivatives mono-functionalized with carboxylic and primary amine groups were investigated. The presence of a carboxylic and amine group attached to the triphenylene core generated stable, thermo- and pH-sensitive supramolecular π-organogels with a reversible response to both stimuli. In order to understand the gelation process, we studied the effect of the spacer length and found a different gelation scope for the acid and basic derivatives that accounts for a different supramolecular self-assembly. The presence of the basic group on the amino derivatives was used to guide and catalyze the templated in situ sol-gel polymerization of TEOS and allowed us, under controlled hydrolytic conditions, to prepare an entangled fibrillar network of silica nanotubes.

机译：研究了用羧基和伯胺基单官能化的六种不对称六醚六亚苯基联苯衍生物的胶凝性能和自组装方式。附着在三亚苯基核心上的羧基和胺基的存在会产生稳定的，对热和pH敏感的超分子π-有机胶体，对两种刺激均具有可逆的响应。为了理解凝胶化过程，我们研究了间隔物长度的影响，并发现了造成不同超分子自组装的酸和碱性衍生物的不同凝胶化范围。氨基衍生物上碱性基团的存在用于指导和催化TEOS模板化的原位溶胶-凝胶聚合，并允许我们在受控的水解条件下制备二氧化硅纳米管的缠结纤维状网络。

著录项

来源
《Gels》 |2016年第1期|共页
作者
Ignacio Mu?oz Resta; Verónica E. Manzano; Florencia Cecchi; Carla C. Spagnuolo; Fabio D. Cukiernik; Pablo H. Di Chenna;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类生物物理学;
关键词

相似文献

外文文献
中文文献
专利

1. Supramolecular gels from lipopeptide gelators: Template improvement and strategies for the in-situ preparation of inorganic nanomaterials and for the dispersion of carbon nanomaterials [J] . Frederic Delbecq Advances in colloid and interface science . 2014,第Null期

机译：脂肽胶凝剂的超分子凝胶：模板改进和无机纳米材料原位制备以及碳纳米材料分散的策略
2. Preparation of Mesoscale and Macroscale Silica Nanotubes Using a Sugar-Appended Azonaphthol Gelator Assembly [J] . Jong Hwa Jung, Seiji Shinkai, Toshimi Shimizu Nano letters . 2002,第1期

机译：使用添加糖的Azonaphthol胶凝剂组件制备中尺度和大尺度二氧化硅纳米管
3. The effect of vicinal di-halo substituents on the organogelling properties of aromatic supramolecular gelators and their application as soft templates [J] . Mac Cormack Andrea S., Busch Veronica M., Laura Japas M., New Journal of Chemistry . 2020,第20期

机译：邻离偶氮取代基对芳香族超分子胶凝胶剂的有机凝胶性能的影响及其作为软模板的应用
4. Supramolecular Self-assembly in a Disk-Cube Dyad Molecule based on Triphenylene and Polyhedral Oligomeric Silsesquioxane (POSS) [C] . Li Cui, Jeffrey P. Collet, Lei Zhu PMSE Symposia . 2007

机译：基于三苯基和多面体低聚Silsesquioxane（POSS）的硬质分子自组装在盘立方体二元分子中
5. Supramolecular assembly of mesoporous silicas with Gemini surfactants and microemulsion templating: Synthesis, characterization and catalysis. [D] . Karkamkar, Abhijeet Jayant. 2003

机译：介孔二氧化硅与Gemini表面活性剂的超分子组装和微乳液模板：合成，表征和催化。
6. Supramolecular Assembly of pH-Sensitive Triphenylene Derived π-Gelators and Their Application as Molecular Template for the Preparation of Silica Nanotubes [O] . Ignacio Muñoz Resta, Verónica E. Manzano, Florencia Cecchi, 2016

机译：pH敏感的三亚苯基衍生的π-胶凝体的超分子组装及其作为制备硅胶纳米管的分子模板的应用
7. Supramolecular Assembly of pH-Sensitive Triphenylene Derived π-Gelators and Their Application as Molecular Template for the Preparation of Silica Nanotubes [O] . Ignacio Muñoz Resta, Verónica E. Manzano, Florencia Cecchi, 2016

机译：pH敏感型三苯撑衍生π-凝胶剂的超分子组装及其作为二氧化硅纳米管制备的分子模板的应用

Supramolecular Assembly of pH-Sensitive Triphenylene Derived π-Gelators and Their Application as Molecular Template for the Preparation of Silica Nanotubes

摘要

著录项

相似文献

相关主题

期刊订阅