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Mathematical Modeling Analysis and Optimization of Key Design Parameters of Proton-Conductive Solid Oxide Fuel Cells

机译:质子传导固体氧化物燃料电池关键设计参数的数学建模分析与优化

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A proton-conductive solid oxide fuel cell (H-SOFC) has the advantage of operating at higher temperatures than a PEM fuel cell, but at lower temperatures than a SOFC. This study proposes a mathematical model for an H-SOFC in order to simulate the performance and optimize the flow channel designs. The model analyzes the average mass transfer and species' concentrations in flow channels, which allows the determination of an average concentration polarization in anode and cathode gas channels, the proton conductivity of electrolyte membranes, as well as the activation polarization. An electrical circuit for the current and proton conduction is applied to analyze the ohmic losses from an anode current collector to a cathode current collector. The model uses relatively less amount of computational time to find the V-I curve of the fuel cell, and thus it can be applied to compute a large amount of cases with different flow channel dimensions and operating parameters for optimization. The modeling simulation results agreed satisfactorily with the experimental results from literature. Simulation results showed that a relatively small total width of flow channel and rib, together with a small ratio of the rib's width versus the total width, are preferable for obtaining high power densities and thus high efficiency.
机译:质子传导性固体氧化物燃料电池(H-SOFC)具有在比PEM燃料电池更高的温度下但在比SOFC更低的温度下工作的优点。这项研究提出了一种H-SOFC的数学模型,以模拟性能并优化流道设计。该模型分析了流动通道中的平均质量传递和物质浓度,从而可以确定阳极和阴极气体通道中的平均浓度极化,电解质膜的质子电导率以及活化极化。施加用于电流和质子传导的电路以分析从阳极集电器到阴极集电器的欧姆损耗。该模型使用相对较少的计算时间来查找燃料电池的V-I曲线,因此可以用于计算大量具有不同流道尺寸和运行参数的情况以进行优化。建模仿真结果与文献中的实验结果令人满意。仿真结果表明,流道和肋的总宽度相对较小,并且肋的宽度与总宽度之比较小,对于获得高功率密度并因此获得高效率是优选的。

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