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Limits Imposed by the Second Law of Thermodynamics on Reducing Greenhouse Gas Emissions to the Atmosphere

机译:热力学第二定律对减少温室气体向大气排放的限制

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Background and Objective: Society is moving toward unconventional oil and gas exploitation and greenhouse gas emissions reduction. The main objective of this research is to develop an exergy based conceptual framework that integrates all aspects of fuel production from resource extraction to environmental protection, including CO2 abatement. Materials and Methods: A multistep deterministic method, from Carnot to exergy analysis, is used to develop a conceptual framework with the help of information from the literature. The approach used in this study mirrors some initial steps in the development of exergy analysis that can be found in Carnot’s work, but the focus is on resource flow rather than maximum work or efficiency. The hypothesis that the flow of fossil resources to produce fuel is related to source-sink properties explored with a simple case related to heat transfer . The possible transposition of this simple case to fuel production is examined to provide insights into the possible uses of the conceptual development. Results: This paper proposes an exergy based conceptual source-sink approach, following Carnot’s theory, to understand the complex problem of fuel production in relation to CO2 abatement. The source is defined by natural resources and their associated quality and one sink is the atmosphere or any CO2 confinement option. Conclusion: The proposed conceptual framework for source-sink exergy analysis of resource flow could improve our understanding of the thermodynamic limits and the sustainability of energy and material production.
机译:背景与目标:社会正在朝着非常规的油气开采和减少温室气体排放的方向发展。这项研究的主要目的是开发一种基于火用的概念框架,该框架将燃料生产从资源提取到环境保护的各个方面进行整合,包括减少CO 2 。材料和方法:从卡诺(Carnot)到火用分析的多步骤确定性方法,用于借助文献信息来开发概念框架。本研究中使用的方法反映了在卡诺的工作中发现的开发能值分析的一些初始步骤,但重点是资源流动而不是最大的工作或效率。假设化石资源生产燃料的流量与源汇性质有关的假设是通过与传热有关的简单案例探讨的。研究了这种简单情况到燃料生产的可能转换,以提供对概念开发的可能用途的见解。结果:本文根据卡诺(Carnot)的理论,提出了一种基于火用的概念性源汇方法,以了解与CO 2 减排相关的复杂燃料生产问题。来源由自然资源及其相关的质量定义,一个汇是大气或任何CO 2 限制选项。结论:为资源流的源-汇火用分析提出的概念框架可以增进我们对热力学极限以及能源和材料生产可持续性的理解。

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