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首页> 外文期刊>Reviews on Advanced Materials Science >Hybrid Inorganic/Organic Polymers with Nanoscale Building Blocks: Precursors,Processing, Properties and Applications
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Hybrid Inorganic/Organic Polymers with Nanoscale Building Blocks: Precursors,Processing, Properties and Applications

机译：具有纳米结构单元的无机/有机杂化聚合物：前体，工艺，性能和应用

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Hybrid polymers (ORMOCERO?s, Ceramers) are composites with inorganic and organic nanobuilding blocks linked via stable covalent bonds based on organically modified silicon alkoxides and/or functionalized organic oligomers/polymers. A method often used is the formation of the inorganic network by polycondensation reactions (e.g. Si-O-Si bond formation) in a first step, followed by the organic crosslinking (thermal curing at 80–180 °C or UV-processing). Another type uses the silylation of organic polymers, with subsequent hydrolysis and polycondensation reactions of the silanized units. The paper focuses on the selection of precursors for various applications and the chemistry involved in processing. Basic properties and the application potential of ORMOCERO?s as coatings, fibers and composites are presented. Property/composition relationships are shown for mechanical and permeation/barrier properties.
机译：杂化聚合物（ORMOCERO ？ s，Ceramers）是具有无机和有机纳米结构单元的复合材料，该结构单元通过基于有机改性的硅醇盐和/或功能化的有机低聚物/聚合物的稳定的共价键相连。常用的方法是第一步通过缩聚反应（例如形成Si-O-Si键）形成无机网络，然后进行有机交联（80-180°C的热固化或UV处理）。另一种类型使用有机聚合物的甲硅烷基化，随后进行硅烷化单元的水解和缩聚反应。本文着重于为各种应用选择前体，以及涉及加工的化学物质。介绍了ORMOCERO ？ s的基本性能及其在涂料，纤维和复合材料中的应用前景。显示了机械/渗透/阻隔性能的性质/组成关系。

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