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首页> 外文期刊>Revista Eletrnica de Farmácia >ELECTROCHEMICAL BEHAVIOR OF VULPINIC ACID AT GLASSY CARBON ELECTRODE
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ELECTROCHEMICAL BEHAVIOR OF VULPINIC ACID AT GLASSY CARBON ELECTRODE

机译:玻碳碳电极上乙酸的电化学行为

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The electrochemical redox behavior of vulpic acid, a lichen derivative, mainly investigated by its antibiotic activity was carried out in aqueous electrolytes at glassy carbon electrode. This investigation was developed by using cyclic, differential pulse and square wave voltammetry in a wide range of pH. Thus, the electrochemical oxidation of vulpic acid showed to occur in a single anodic and irreversible process with strong adsorption of oxidation products. The oxidation of adsorbed species leads to a second anodic peak, meanwhile the first anodic peak decreases intensely. Such events showed to be higher in non-neutral pH, and should be associated to hydrolysis of lactone.
机译:主要通过其抗生素活性研究的地衣衍生物-硫氰酸的电化学氧化还原行为是在玻璃碳电极上的水性电解质中进行的。该研究是通过在较宽的pH范围内使用循环,差分脉冲和方波伏安法进行的。因此,在单一的阳极和不可逆的过程中,具有强烈的氧化产物吸附作用,可进行硫化氢的电化学氧化。吸附物质的氧化导致第二个阳极峰,而第一个阳极峰急剧减少。这种事件在非中性pH值较高,应与内酯水解有关。

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