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Synthesis and evaluation of an oil-soluble viscosity reducer for heavy oil

机译:稠油油溶性降粘剂的合成与评价

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摘要

To reduce the viscosity of highly-viscous oil of the Tahe oilfield (Xinjiang, China), an oilsoluble polybasic copolymer viscosity reducer for heavy oil was synthesized using the orthogonal method. The optimum reaction conditions are obtained as follows: under the protection of nitrogen, a reaction time of 9 h, monomer mole ratio of reaction materials of 3:2:2 (The monomers are 2-propenoic acid, docosyl ester, maleic anhydride and styrene, respectively), initiator amount of 0.8% (mass percent of the sum of all the monomers) and reaction temperature of 80 °C. This synthesized viscosity reducer is more effective than commercial viscosity reducers. The rate of viscosity reduction reached 95.5% at 50 °C. Infrared spectra (IR) and interfacial tensions of heavy oil with and without viscosity reducer were investigated to understand the viscosity reduction mechanism. When viscosity reducer is added, the molecules of the viscosity reducer are inserted amongst the molecules of crude oil, altering the original intermolecular structure of crude oil and weakening its ability to form hydrogen bonds with hydroxyl or carboxyl groups, so the viscosity of crude oil is reduced. Field tests of the newly developed oil-soluble viscosity reducer was carried out in the Tahe Oilfield, and the results showed that 44.5% less light oil was needed to dilute the heavy oil to achieve the needed viscosity.
机译:为了降低塔河油田(中国新疆)的高粘度油的粘度,使用正交方法合成了一种油溶性多元油多元共聚物稠油降粘剂。最佳反应条件为:在氮气保护下,反应时间为9 h,反应物料的单体摩尔比为3:2:2(单体为2-丙酸,二十二烷基酯,马来酸酐和苯乙烯) ,引发剂的量分别为0.8%(所有单体总量的质量百分比),反应温度为80°C。该合成的减粘剂比市售的减粘剂更有效。在50℃下粘度降低率达到95.5%。研究了使用和不使用减粘剂的重油的红外光谱(IR)和界面张力,以了解减粘机理。当添加减粘剂时,该减粘剂的分子被插入到原油分子中,从而改变了原油的原始分子间结构并削弱了其与羟基或羧基形成氢键的能力,因此原油的粘度为减少。在塔河油田对新开发的油溶性降粘剂进行了现场测试,结果表明,稀释重油以达到所需的粘度所需的轻油量减少了44.5%。

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