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首页> 外文期刊>Physics and Materials Chemistry >α- Zirconium Titanium Phosphates - Fibrous Cerium Phosphate Composite Membranes and Their 1,10- Phenanthroline Cu(II) Pillared Materials
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α- Zirconium Titanium Phosphates - Fibrous Cerium Phosphate Composite Membranes and Their 1,10- Phenanthroline Cu(II) Pillared Materials

机译：α-磷酸锆钛-纤维状磷酸铈复合膜及其1,10-菲咯啉Cu（II）柱状材料

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摘要

Nanosized fibrous cerium phosphate, Ce(HPO4)2.2.9H2O(nCePf), and α- Zirconium -Titanium Phosphates, ZrxTi1-x(HPO4)2.H2O(α-ZTP), where x = 0.9, 0.8, 0. 67, 0.34, were synthesized. Novel composite membranes [ZrxTi(1-x)(HPO4)2]0.25 [Ce(HPO4)2]0.75 .3.3H2O were prepared. Reactions of the resulting composite membranes with 1,10-phenanthroline in ethanol, followed by the addition of 0.1M CuCl2.2H2O, in (1:1) ethanol: aqueous solution, lead to the formation of novel pillared materials: [(H1.16) Zr0.9Ti0.1 (PO4)2]0.25[(H1.16 ) Ce (PO4)2]0.75(PhenCu)0.42.2.25H2O, [(H1.5)Zr0.8Ti0.2 (PO4)2]0.25 [( H1.5)Ce (PO4)2] 0.75 (Phen Cu)0.25.1.77H2O, [(H0.3 ) Zr0.67Ti (PO4)2] 0.25 [(H 0.3) Ce (PO4)2]0.75.(Phen Cu)0.85. 4H2O, [(H1.6)Zr0.34Ti0.66 (PO4)2]0.25 [(H1.6) Ce (PO4)2]0.75.(PhenCu)0.2. 2.22 H2O, respectively. They were characterized by chemical, X-ray diffraction (XRD) and thermal analysis (TGA), accordingly were formulated. XRD patterns of the composite materials retain (d) spacing reflection of α-ZTP and nCePf, where d001 = 7.58 ? and 11.38 ?, respectively, The resulting composites are thermally stable and can be considered as novel ecofriendly solid acid catalysts, Ionex changers and ionc conductance materials.
机译：纳米纤维磷酸铈Ce（HPO4）2.2.9H2O（nCePf）和α-锆钛酸磷酸盐ZrxTi1-x（HPO4）2.H2O（α-ZTP），其中x = 0.9、0.8、0。67， 0.34，被合成。制备了新型复合膜[ZrxTi（1-x）（HPO4）2] 0.25 [Ce（HPO4）2] 0.75.3.3H2O。所得复合膜与1,10-菲咯啉在乙醇中的反应，然后在（1：1）乙醇：水溶液中添加0.1M CuCl2.2H2O，导致形成新型柱状材料：[[H1。 16）Zr0.9Ti0.1（PO4）2] 0.25 [（H1.16）Ce（PO4）2] 0.75（PhenCu）0.42.2.25H2O，[（H1.5）Zr0.8Ti0.2（PO4）2] 0.25 [（H1.5）Ce（PO4）2] 0.75（苯铜）0.25.1.77H2O，[（H0.3）Zr0.67Ti（PO4）2] 0.25 [（H 0.3）Ce（PO4）2] 0.75 。（苯铜）0.85。 4H 2 O，[（H1.6）Zr0.34Ti0.66（PO4）2] 0.25 [（H1.6）Ce（PO4）2] 0.75。（PhenCu）0.2。分别为2.22 H2O。通过化学，X射线衍射（XRD）和热分析（TGA）对它们进行了表征，并据此进行了配制。复合材料的XRD图谱保留了（d）α-ZTP和nCePf的间隔反射，其中d001 = 7.58？所得的复合材料是热稳定的，并且可以认为是新型的生态友好型固体酸催化剂，Ionex转化剂和离子导电性材料，其热稳定性分别为11.38和11.38Ω。

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