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Determination of Cd and Pb in fuel ethanol by filter furnace electrothermal atomic absorption spectrometry

机译:过滤炉电热原子吸收光谱法测定燃料乙醇中的镉和铅。

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A method was developed for quantification of Cd and Pb in ethanol fuel by filter furnace atomic absorption spectrometry. Filter furnace was used to eliminate the need for chemical modification, to stabilize volatile analytes and to allow the application of short pyrolysis step. The determinations in samples were carried out against calibration solutions prepared in ethanol. Recovery tests were made in seven commercial ethanol fuel samples with values between 90 and 120%. Limits of detection were 0.1 µg L-1 for Cd and 0.3 µg L-1 for Pb. Certified water samples (APS 1071, APS 1033, NIST 1643d, NIST 1640) were also used to evaluate accuracy and recoveries from 86.8% to115% were obtained.
机译:开发了一种通过过滤炉原子吸收光谱法定量乙醇燃料中镉和铅的方法。使用过滤炉消除了化学修饰的需要,稳定了挥发性分析物,并允许进行较短的热解步骤。样品中的测定是针对在乙醇中制备的校准溶液进行的。在七个商业乙醇燃料样品中进行了回收率测试,样品值在90%至120%之间。检出限为Cd为0.1 µg L-1和Pb为0.3 µg L-1。认证的水样(APS 1071,APS 1033,NIST 1643d,NIST 1640)也用于评估准确性,回收率从86.8%至115%。

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