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Aromaticity: historical evolution of the concept and quantitative criteria

机译:芳香性:概念和定量标准的历史演变

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In this paper the evolution of the concept of aromaticity is discussed. It considers not only historical aspects of the aromaticity concept but also the different criteria (theoretical and experimental) that have appeared to explain the properties of the aromatic compounds. The topics range from the isolation of benzene by Faraday (1825) until the modern criteria based on geometries, magnetic properties, resonance energy (RE), aromatic stabilization energy (ASE), topological analyses, and others. A chronological separation of issues concerning aromaticity was made, splitting the definitions before and after the appearance of the quantum chemistry. This work reviews the concept of aromaticity.
机译:在本文中,讨论了芳香性概念的演变。它不仅考虑了芳香性概念的历史方面,而且考虑了似乎可以解释芳香族化合物特性的不同标准(理论和实验)。主题涉及从法拉第(1825)分离苯到基于几何形状,磁性,共振能(RE),芳族稳定能(ASE),拓扑分析等的现代标准。按时间顺序对涉及芳香性的问题进行了分离,从而在出现量子化学之前和之后将定义进行了划分。这项工作回顾了芳香性的概念。

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