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Stretching a Semiflexible Polymer in a Tube

机译:在管中拉伸半柔性聚合物

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How the statistical behavior of semiflexible polymer chains may be affected by force stretching and tube confinement is a classical unsolved problem in polymer physics. Based on the Odijk deflection theory and normal mode decomposition in terms of Fourier expansion, we have derived a new compact formula for the extension of a wormlike chain of finite length strongly confined in a tube and simultaneously stretched by an external force. We have also suggested a new deflection length, which together with the force-extension relation is valid for a very extended range of the tube-diameter/persistence-length ratio comparing to the classic Odijk theory. The newly derived formula has no adjustable fitting parameters for the whole deflection regime; in contrast, the classic Odijk length needs different prefactors to fit the free energy and average extension, respectively. Brownian dynamics simulations based on the Generalized Bead-Rod (GBR) model were extensively performed, which justified the theoretical predictions.
机译:半柔韧性聚合物链的统计行为如何受到力的拉伸和管子约束的影响是高分子物理学中一个经典的未解决的问题。基于Odijk挠度理论和就傅里叶展开而言的正态分解,我们导出了一个新的紧致公式,用于扩展有限长度的蠕虫状链的延伸,该蠕虫链强烈地约束在管中,并同时受到外力拉伸。我们还提出了一个新的挠曲长度,与经典的奥迪克理论相比,它与力-延伸关系一起对于很大的管径/持久性长度比范围有效。新推导的公式没有针对整个挠度范围的可调拟合参数;相比之下,经典Odijk长度分别需要不同的因子来适应自由能和平均延伸。广泛地进行了基于广义珠-罗德(GBR)模型的布朗动力学模拟,这为理论预测提供了依据。

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