Novel Organic Sensitizers Containing 2,6-Difunctionalized Anthracene Unit for Dye Sensitized Solar Cells

Hsien-Hsin Chou; Jiann T. Lin; Shih-Tang Huang; Yung-Chung Chen; Yung-Sheng Yen

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Novel Organic Sensitizers Containing 2,6-Difunctionalized Anthracene Unit for Dye Sensitized Solar Cells

机译：用于染料敏化太阳能电池的新型有机敏化剂，含2,6-双官能团蒽单元

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A series of new organic dyes comprising different amines as electron donors, 2-(6-substituted-anthracen-2-yl)-thiophene as the π-conjugated bridge, and cyanoacrylic acid group as an electron acceptor and anchoring group, have been synthesized. There exists charge transfer transition from arylamine and anthracene to the acceptor in these compounds, as evidenced from the photophysical measurements and the computational results. Under one sun (AM 1.5) illumination, dye-sensitized solar cells (DSSCs) using these dyes as the sensitizers exhibited efficiencies ranging from 1.62% to 2.88%, surpassing that using 9,10-difunctionalized anthracene-based sensitizer.

机译：合成了一系列新的有机染料，其中包含不同的胺作为电子供体，2-（6-取代的蒽-2-基）-噻吩作为π-共轭桥，氰基丙烯酸基团作为电子受体和锚定基团。这些化合物存在从芳基胺和蒽到受体的电荷转移跃迁，从光物理测量和计算结果可以证明。在一种阳光（AM 1.5）照射下，使用这些染料作为敏化剂的染料敏化太阳能电池（DSSC）的效率范围为1.62％至2.88％，超过了使用9,10-双官能团蒽基敏化剂的效率。

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《Polymers》 |2012年第3期|共19页
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Hsien-Hsin Chou; Jiann T. Lin; Shih-Tang Huang; Yung-Chung Chen; Yung-Sheng Yen;
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2. 2,6-Conjugated anthracene sensitizers for high-performance dye-sensitized solar cellst [J] . Ryan Yeh-Yung Lin, Hung-Wen Lin, Yung-Sheng Yen, Energy & environmental science . 2013,第8期

机译：2,6-共轭蒽敏化剂，用于高性能染料敏化太阳能电池
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4. A Series of New Organic D-A-π-A Sensitizers containing Pyridal2,1,3thiadiazole Unit for Dye-sensitized Solar Cells [C] . Weijiang Ying, Jing Li, Jianli Hua The 22nd International photovoltaic science and engineering conference . 2012

机译：一系列含有吡啶并2,1,3噻二唑单元的新型有机D-A-π-A敏化剂，用于染料敏化太阳能电池
5. Molecular Engineering of Ruthenium-based Sensitizers and Metal-Free Organic Sensitizers with Panchromatic Chromophores for Highly Efficient Dye-Sensitized Solar Cells [D] . Su, Rui. 2019

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6. Tailoring of Energy Levels in D-π-A Organic Dyes via Fluorination of Acceptor Units for Efficient Dye-Sensitized Solar Cells [O] . Min-Woo Lee, Jae-Yup Kim, Hae Jung Son, -1

机译：通过高效染料敏化太阳能电池受体单元的氟化来调节D-π-A有机染料的能级
7. Novel Organic Sensitizers Containing 2,6-Difunctionalized Anthracene Unit for Dye Sensitized Solar Cells [O] . Jiann T. Lin, Shih-Tang Huang, Yung-Sheng Yen, 2012

机译：用于染料敏化太阳能电池的含有2,6-双官能化蒽单元的新型有机增感剂

Novel Organic Sensitizers Containing 2,6-Difunctionalized Anthracene Unit for Dye Sensitized Solar Cells

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