Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl 4 ] ?

Javier López-Cabrelles; Guillermo Mínguez Espallargas; Eugenio Coronado

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Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl 4 ] ?

机译：MOMOF中的单晶至单晶阴离子交换：POM和[AuCl 4]的掺入

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The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl 4 ] ? . This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.

机译：近年来，在多功能材料领域中，在多孔配位聚合物（也称为金属有机骨架，MOF）中的功能分子的封装引起了极大的兴趣。在本文中，我们对基于Gd的MOF的阴离子交换过程中尺寸和电荷的影响进行了研究，涉及分子种类如多金属氧酸盐（POMs）和[AuCl 4]α。。这种合成后的修饰已通过IR，EDAX和单晶衍射进行了表征，这为阴离子分子在骨架中的位置提供了明确的证据。

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《Polymers》 |2016年第5期|共页
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Javier López-Cabrelles; Guillermo Mínguez Espallargas; Eugenio Coronado;
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1. Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal-organic framework [J] . Manna Biplab, Desai Aamod V., Kumar Naveen, CrystEngComm . 2015,第46期

机译：可阴离子交换的动态金属有机骨架的单晶至单晶转变
2. Anion-exchangeable modulated fluorescence strategy for sensitive ascorbic acid detection with luminescent Eu hydroxy double salts nanosunflowers derived from MOFs [J] . Li Ali, Zhang Jie, Sun Shihao, Sensors and Actuators . 2019,第OCTa期

机译：阴离子交换的调制荧光策略用于灵敏的抗坏血酸检测，其衍生自MOF的发光Eu羟基双盐纳米向日葵
3. Anion-exchangeable modulated fluorescence strategy for sensitive ascorbic acid detection with luminescent Eu hydroxy double salts nanosunflowers derived from MOFs [J] . Li Ali, Zhang Jie, Sun Shihao, Sensors and Actuators . 2019,第Octa期

机译：用于敏感抗坏血酸检测的阴离子可交换的调节荧光策略与MOFs的发光EU羟基双盐纳米春
4. MODELLING OF STRONG-ACID CATION/ STRONG-BASE ANION MIXED-BEDION EXCHANGE OF GADOLINIUM NITRATE FROM DILUTE SOLUTION [C] . Duncan H. Barber The New Nuclear Generation . 2005

机译：稀溶液中硝酸G强酸阳离子/强碱阴离子混合床交换模型
5. Preparations and Characterizations of Anion Exchange Membranes and Ionomers for Anion Exchange Membrane Fuel Cells. [D] . Zeng, Lin. 2014

机译：用于阴离子交换膜燃料电池的阴离子交换膜和离聚物的制备和表征。
6. Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and AuCl4− [O] . Javier López-Cabrelles, Guillermo Mínguez Espallargas, Eugenio Coronado 2016

机译：MOMOF中的单晶至单晶阴离子交换：POM和AuCl4-的掺入
7. Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]− [O] . Javier López-Cabrelles, Guillermo Mínguez Espallargas, Eugenio Coronado 2016

机译：钆mOF中的单晶 - 单晶阴离子交换：pOm和[auCl4]的结合 -
8. Beta -(BEDT-TTF)2 -AuCl4 : Importance of Hydrogen-Anion Interactions in a Desctructive Phase Transition Observed at Low Temperatures. [R] . Geiser, U., Wang, H. H., Anderson, B. A., 1989

机译：β - （BEDT-TTF）2 -auCl4：在低温下观察到的破坏性相变中氢 - 阴离子相互作用的重要性。

Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl 4 ] ?

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