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Layer-by-Layer Assembly of Polyelectrolyte Multilayer onto PET Fabric for Highly Tunable Dyeing with Water Soluble Dyestuffs

机译:聚电解质多层在PET织物上的分层组装,用于水溶性染料的高度可调染色

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Poly(ethyleneterephthalate) (PET) is a multi-purpose and widely used synthetic polymer in many industrial fields because of its remarkable advantages such as low cost, light weight, high toughness and resistance to chemicals, and high abrasion resistance. However, PET suffers from poor dyeability due to its non-polar nature, benzene ring structure as well as high crystallinity. In this study, PET fabrics were firstly treated with an alkaline solution to produce carboxylic acid functional groups on the surface of the PET fabric, and then was modified by polyelectrolyte polymer through the electrostatic layer-by-layer self-assembly technology. The polyelectrolyte multilayer-deposited PET fabric was characterized using scanning electron microscopy SEM, contact angle, Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS). The dyeability of PET fabrics before and after surface modification was systematically investigated. It showed that the dye-uptake of the polyelectrolyte multilayer-deposited PET fabric has been enhanced compared to that of the pristine PET fabric. In addition, its dyeability is strongly dependent on the surface property of the polyelectrolyte multilayer-deposited PET fabric and the properties of dyestuffs.
机译:聚对苯二甲酸乙二酯(PET)具有低成本,重量轻,高韧性和耐化学药品性以及高耐磨性等显着优势,是许多工业领域中用途广泛的合成聚合物。然而,PET由于其非极性性质,苯环结构以及高结晶度而具有差的可染性。在这项研究中,首先用碱性溶液处理PET织物,以在PET织物的表面上产生羧酸官能团,然后再通过静电逐层自组装技术对聚电解质聚合物进行改性。使用扫描电子显微镜SEM,接触角,傅立叶变换红外(FTIR)和X射线光电子能谱(XPS)对聚电解质多层沉积的PET织物进行表征。系统地研究了PET织物表面改性前后的可染性。结果表明,与原始PET织物相比,聚电解质多层沉积的PET织物的染料吸收得到提高。另外,其可染性在很大程度上取决于聚电解质多层沉积的PET织物的表面性质和染料的性质。

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